Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions

K Das, S Waiba, A Jana, B Maji - Chemical Society Reviews, 2022 - pubs.rsc.org
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

ES Gulyaeva, ES Osipova, R Buhaibeh… - Coordination Chemistry …, 2022 - Elsevier
Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …

Advancements in multifunctional manganese complexes for catalytic hydrogen transfer reactions

K Das, MK Barman, B Maji - Chemical Communications, 2021 - pubs.rsc.org
Catalytic hydrogen transfer reactions have enormous academic and industrial applications
for the production of diverse molecular scaffolds. Over the past few decades, precious late …

Recent advances in homogeneous base-metal-catalyzed transfer hydrogenation reactions

D Baidilov, D Hayrapetyan, AY Khalimon - Tetrahedron, 2021 - Elsevier
Owing to availability of various hydrogen sources, operational simplicity, and mild reaction
conditions, catalytic transfer hydrogenation (TH) has emerged as an appealing alternative …

The rise of manganese-catalyzed reduction reactions

P Schlichter, C Werlé - Synthesis, 2022 - thieme-connect.com
Recent developments in manganese-catalyzed reducing transformations—hydrosilylation,
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …

Manganese—New prominent actor in transfer hydrogenation catalysis

K Azouzi, DA Valyaev, S Bastin, JB Sortais - Current Opinion in Green and …, 2021 - Elsevier
Highlights•Mn complexes can catalyze transfer hydrogenation of C double bond O, C double
bond N, C double bond C, C triple bond N, and C triple bond C bonds.•Mn-catalyzed transfer …

Manganese‐Catalyzed Asymmetric Formal Hydroamination of Allylic Alcohols: A Remarkable Macrocyclic Ligand Effect

F Li, L Long, YM He, Z Li, H Chen… - Angewandte Chemie, 2022 - Wiley Online Library
A unique family of chiral peraza N6‐macrocyclic ligands, which are conformationally rigid
and have a tunable saddle‐shaped cavity, is described. Utilizing their manganese (I) …

Amino acid derived chiral aminobenzimidazole manganese catalysts for asymmetric transfer hydrogenation of ketones

L Wang, J Lin, Q Sun, C **a, W Sun - ACS Catalysis, 2021 - ACS Publications
A series of Mn (I) catalysts with chiral bidentate benzimidazoles derived from easily
available amino acids has been developed. These types of phosphine-free chiral Mn …

Bifunctional homogeneous catalysts based on first row transition metals in asymmetric hydrogenation

F Agbossou-Niedercorn, C Michon - Coordination Chemistry Reviews, 2020 - Elsevier
This article reviews over the past 10 years the development of bifunctional homogeneous
catalysts based on first row transition metals for asymmetric hydrogenation of various CC …

ReNeGate: A reaction network graph-theoretical tool for automated mechanistic studies in computational homogeneous catalysis

A Hashemi, S Bougueroua, MP Gaigeot… - Journal of chemical …, 2022 - ACS Publications
Exploration of the chemical reaction space of chemical transformations in multicomponent
mixtures is one of the main challenges in contemporary computational chemistry. To remove …