Advancements in electrochemical methanol synthesis from CO2: Mechanisms and catalyst developments
Abstract Electrochemical CO 2 reduction (eCO 2 R) has emerged as a promising avenue,
offering the dual benefits of mitigating atmospheric CO 2 while generating value-added …
offering the dual benefits of mitigating atmospheric CO 2 while generating value-added …
Revolutionizing electrochemical CO 2 reduction to deeply reduced products on non-Cu-based electrocatalysts
Producing deeply reduced (net number of electrons transferred per carbon atom greater
than two,> 2e−) products from electrochemical CO2 reduction reaction (eCO2RR) is an …
than two,> 2e−) products from electrochemical CO2 reduction reaction (eCO2RR) is an …
The solvation environment of molecularly dispersed cobalt phthalocyanine determines methanol selectivity during electrocatalytic CO2 reduction
Heterogenized molecular electrocatalysts are a promising group of materials that can
electrocatalytically convert waste molecules into higher-value products. However, how the …
electrocatalytically convert waste molecules into higher-value products. However, how the …
Value‐Added Cascade Synthesis Mediated by Paired‐Electrolysis Using an Ultrathin Microenvironment‐Inbuilt Metalized Covalent Organic Framework …
Q Li, DD Ma, WB Wei, SG Han… - Advanced Energy …, 2024 - Wiley Online Library
Energy‐saving and value‐added management in advanced catalysis is highly desirable but
is challenged by the limitations of multifunctional catalysts and catalytic modules. Herein, an …
is challenged by the limitations of multifunctional catalysts and catalytic modules. Herein, an …
Potential-driven structural distortion in cobalt phthalocyanine for electrocatalytic CO2/CO reduction towards methanol
Cobalt phthalocyanine immobilized on carbon nanotube has demonstrated appreciable
selectivity and activity for methanol synthesis in electrocatalytic CO2/CO reduction. However …
selectivity and activity for methanol synthesis in electrocatalytic CO2/CO reduction. However …
Proton-Coupled Electron Transfer Mechanisms for CO2 Reduction to Methanol Catalyzed by Surface-Immobilized Cobalt Phthalocyanine
P Hutchison, LE Smith, CL Rooney… - Journal of the …, 2024 - ACS Publications
Immobilized cobalt phthalocyanine (CoPc) is a highly promising architecture for the six-
proton, six-electron reduction of CO2 to methanol. This electroreduction process relies on …
proton, six-electron reduction of CO2 to methanol. This electroreduction process relies on …
Tailoring Interfaces for Enhanced Methanol Production from Photoelectrochemical CO2 Reduction
Efficient and stable photoelectrochemical reduction of CO2 into highly reduced liquid fuels
remains a formidable challenge, which requires an innovative semiconductor/catalyst …
remains a formidable challenge, which requires an innovative semiconductor/catalyst …
Electrochemical CO2 Reduction to Methanol by Cobalt Phthalocyanine: Quantifying CO2 and CO Binding Strengths and Their Influence on Methanol Production
Cobalt phthalocyanine (CoPc) is an active electrocatalyst for the sequential electrochemical
reductions of CO2-to-CO and CO-to-methanol (CH3OH), and it has been shown to be active …
reductions of CO2-to-CO and CO-to-methanol (CH3OH), and it has been shown to be active …
Subtle Modifications in Interface Configurations of Iron/Cobalt Phthalocyanine‐Based Electrocatalysts Determine Molecular CO2 Reduction Activities
Strain engineering has emerged as a powerful approach in steering material properties.
However, the mechanism and potential limitations remain poorly understood. Here we report …
However, the mechanism and potential limitations remain poorly understood. Here we report …
Nonadiabatic proton-coupled electron transfer at a graphitic surface immobilized cobalt porphyrin
Immobilized molecular electrocatalysts can exhibit altered proton-coupled electron transfer
(PCET) chemistry compared to their nonimmobilized counterparts. Recent experiments …
(PCET) chemistry compared to their nonimmobilized counterparts. Recent experiments …