Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Recent advances of single-atom catalysts in CO 2 conversion

S Wang, L Wang, D Wang, Y Li - Energy & Environmental Science, 2023 - pubs.rsc.org
The catalytic transformation of CO2 into valuable fuels/chemicals is a promising and
economically profitable process because it offers an alternative toward fossil feedstocks and …

Single‐atom Bi alloyed Pd metallene for nitrate electroreduction to ammonia

K Chen, Z Ma, X Li, J Kang, D Ma… - Advanced Functional …, 2023 - Wiley Online Library
Electrochemical reduction of nitrate to ammonia (NO3RR) holds a great promise for attaining
both NH3 electrosynthesis and wastewater purification. Herein, single‐atom Bi alloyed Pd …

Intermetallic single-atom alloy In–Pd bimetallene for neutral electrosynthesis of ammonia from nitrate

M **e, S Tang, Z Li, M Wang, Z **, P Li… - Journal of the …, 2023 - ACS Publications
Harvesting recyclable ammonia (NH3) from the electrocatalytic reduction of nitrate (NO3RR)
offers a sustainable strategy to close the ecological nitrogen cycle from nitration …

Emerging applications, developments, prospects, and challenges of electrochemical nitrate‐to‐ammonia conversion

W Chen, X Yang, Z Chen, Z Ou, J Hu… - Advanced Functional …, 2023 - Wiley Online Library
Ammonia is not only an important feedstock for chemical industry but also a carbon‐free
energy carrier and a safe storage media for hydrogen. Due to the advantages compared to …

Selective Photocatalytic Reduction of CO2 to CO Mediated by Silver Single Atoms Anchored on Tubular Carbon Nitride

S Hu, P Qiao, X Yi, Y Lei, H Hu, J Ye… - Angewandte Chemie …, 2023 - Wiley Online Library
Artificial photosynthesis is a promising strategy for converting carbon dioxide (CO2) and
water (H2O) into fuels and value‐added chemical products. However, photocatalysts usually …

Tandem electrocatalytic reduction of nitrite to ammonia on rhodium–copper single atom alloys

J **ang, C Qiang, S Shang, K Chen… - Advanced Functional …, 2024 - Wiley Online Library
Electrocatalytic reduction of NO2− to NH3 (NO2RR) presents a fascinating approach for
simultaneously migrating NO2− pollutants and producing valuable NH3. In this study, single …

Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Challenges and opportunities in engineering the electronic structure of single-atom catalysts

V Giulimondi, S Mitchell, J Pérez-Ramírez - ACS catalysis, 2023 - ACS Publications
Controlling the electronic structure of transition-metal single-atom heterogeneous catalysts
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …

Long‐range interactions in diatomic catalysts boosting electrocatalysis

WH Li, J Yang, D Wang - Angewandte Chemie, 2022 - Wiley Online Library
The simultaneous presence of two active metal centres in diatomic catalysts (DACs) leads to
the occurrence of specific interactions between active sites. Such interactions, referred to as …