[HTML][HTML] Recent developments in the PySCF program package

Q Sun, X Zhang, S Banerjee, P Bao, M Barbry… - The Journal of …, 2020‏ - pubs.aip.org
P y SCF is a Python-based general-purpose electronic structure platform that supports first-
principles simulations of molecules and solids as well as accelerates the development of …

Relativistic heavy-neighbor-atom effects on NMR shifts: Concepts and trends across the periodic table

J Vı́cha, J Novotny, S Komorovsky, M Straka… - Chemical …, 2020‏ - ACS Publications
Chemical shifts present crucial information about an NMR spectrum. They show the
influence of the chemical environment on the nuclei being probed. Relativistic effects …

The DIRAC code for relativistic molecular calculations

T Saue, R Bast, ASP Gomes, HJA Jensen… - The Journal of …, 2020‏ - pubs.aip.org
DIRAC is a freely distributed general-purpose program system for one-, two-, and four-
component relativistic molecular calculations at the level of Hartree–Fock, Kohn–Sham …

[کتاب][B] Relativistic quantum chemistry: the fundamental theory of molecular science

M Reiher, A Wolf - 2015‏ - books.google.com
Einstein proposed his theory of special relativity in 1905. For a long time it was believed that
this theory has no significant impact on chemistry. This view changed in the 1970s when it …

The quantum-chemical calculation of NMR indirect spin–spin coupling constants

T Helgaker, M Jaszuński, M Pecul - Progress in Nuclear Magnetic …, 2008‏ - Elsevier
We present here a review of currently available methods for the calculation of indirect
nuclear spin–spin coupling constants, discussing some of the questions and difficulties …

Theory and computation of nuclear magnetic resonance parameters

J Vaara - Physical Chemistry Chemical Physics, 2007‏ - pubs.rsc.org
The art of quantum chemical electronic structure calculation has over the last 15 years
reached a point where systematic computational studies of magnetic response properties …

Nuclear spin–spin coupling constants from regular approximate relativistic density functional calculations. I. Formalism and scalar relativistic results for heavy metal …

J Autschbach, T Ziegler - The Journal of Chemical Physics, 2000‏ - pubs.aip.org
We present a relativistic formulation of the spin–spin coupling hyperfine terms based on the
two component zeroth-order regular approximate Hamiltonian. The scalar relativistic parts of …

A fully relativistic method for calculation of nuclear magnetic shielding tensors with a restricted magnetically balanced basis in the framework of the matrix Dirac–Kohn …

S Komorovský, M Repiský, OL Malkina… - The Journal of …, 2008‏ - pubs.aip.org
A fully relativistic method for calculation of nuclear magnetic shielding tensors with a
restricted magnetically balanced basis in the framework of the matrix Dirac–Kohn–Sham …

The generalized active space concept for the relativistic treatment of electron correlation. I. Kramers-restricted two-component configuration interaction

T Fleig, J Olsen, CM Marian - The Journal of Chemical Physics, 2001‏ - pubs.aip.org
As a prelude to a series of presentations dealing with the treatment of electron correlation
and special relativity, we present the theoretical background and the implementation of a …

Chemical shift tensors: Theory and application to molecular structural problems

JC Facelli - Progress in nuclear magnetic resonance …, 2010‏ - pmc.ncbi.nlm.nih.gov
Perhaps the most important discovery after the successful detection of the NMR signal was
the observation that nuclear resonance frequencies depend on the chemical or electronic …