Electronic coupling in cyclometalated ruthenium complexes
YW Zhong, ZL Gong, JY Shao, J Yao - Coordination Chemistry Reviews, 2016 - Elsevier
This review summarizes the electronic coupling studies in mixed-valence or donor–acceptor-
type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron …
type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron …
The coordination potential of indigo, anthraquinone and related redox-active dyes
W Kaim, GK Lahiri - Coordination Chemistry Reviews, 2019 - Elsevier
The chromophores of several classes of well-established dyes, eg, indigo, 9, 10-
anthraquinones, formazanes, diketopyrrolopyrroles (DPPs), or certain azo compounds, are …
anthraquinones, formazanes, diketopyrrolopyrroles (DPPs), or certain azo compounds, are …
Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes
A Mandal, B Schwederski, J Fiedler, W Kaim… - Inorganic …, 2015 - ACS Publications
Redox series of the complexes [Ru (L)(L′) 2] n, L= 1, 5-diphenyl-3-(4-tolyl)-formazanate
and L′= 2, 4-pentanedionate (acac–), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine …
and L′= 2, 4-pentanedionate (acac–), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine …
Noninnocence of indigo: dehydroindigo anions as bridging electron-donor ligands in diruthenium complexes
Complexes of singly or doubly deprotonated indigo (H2Ind) with one or two [Ru (pap) 2] 2+
fragments (pap= 2-phenylazopyridine) have been characterized experimentally [molecular …
fragments (pap= 2-phenylazopyridine) have been characterized experimentally [molecular …
Questions of Noninnocence and Ease of Azo Reduction in Diruthenium Frameworks with a 1,8-Bis((E)-phenyldiazenyl)naphthalene-2,7-dioxido Bridge
Ligands containing the azo group are often used in various metal complexes owing to their
facile one-electron reduction, which in effect extends the means of degrading …
facile one-electron reduction, which in effect extends the means of degrading …
Counter-ligand control of the electronic structure in dinuclear copper-tetrakisguanidine complexes
A Ziesak, T Wesp, O Hübner, E Kaifer… - Dalton …, 2015 - pubs.rsc.org
The redox-active GFA (Guanidino-Functionalized Aromatic compound) 1, 4, 5, 8-tetrakis
(tetramethylguanidino)-naphthalene (6) is used to synthesize new dinuclear copper …
(tetramethylguanidino)-naphthalene (6) is used to synthesize new dinuclear copper …
The Electron-Rich {Ru(acac)2} Directed Varying Configuration of the Deprotonated Indigo and Evidence for Its Bidirectional Noninnocence
This article highlights the hitherto unexplored varying binding modes of the deprotonated
natural dye indigo (H2L) and its bidirectional noninnocent potential. The reaction of H2L with …
natural dye indigo (H2L) and its bidirectional noninnocent potential. The reaction of H2L with …
Noninnocently behaving bridging anions of the widely distributed antioxidant ellagic acid in diruthenium complexes
A Mandal, A Grupp, B Schwederski, W Kaim… - Inorganic …, 2015 - ACS Publications
Dinuclear compounds [L2Ru (μ-E) RuL2] n where L is acetylacetonate (acac–, 2, 4-
pentanedionate), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine (pap) and EH4 is ellagic …
pentanedionate), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine (pap) and EH4 is ellagic …
Metal–metal bridging using the DPPP dye system: electronic configurations within multiple redox series
Redox series [L n Ru (μ-DPPP) RuL n] k, H2DPPP= 2, 5-dihydro-3, 6-di-2-pyridylpyrrolo (3,
4-c) pyrrole-1, 4-dione and L= 2, 4-pentanedionato (acac–), 2, 2′-bipyridine (bpy), and 2 …
4-c) pyrrole-1, 4-dione and L= 2, 4-pentanedionato (acac–), 2, 2′-bipyridine (bpy), and 2 …
Redox‐Induced Oxidative C− C Bond Cleavage of 2, 2′‐Pyridil in Diruthenium Complexes
In the recent years, there has been an emerging research interest in the domain of C− C
bond‐cleavage reactions. The present contribution deals with the redox‐mediated dioxygen …
bond‐cleavage reactions. The present contribution deals with the redox‐mediated dioxygen …