Electronic coupling in cyclometalated ruthenium complexes

YW Zhong, ZL Gong, JY Shao, J Yao - Coordination Chemistry Reviews, 2016 - Elsevier
This review summarizes the electronic coupling studies in mixed-valence or donor–acceptor-
type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron …

The coordination potential of indigo, anthraquinone and related redox-active dyes

W Kaim, GK Lahiri - Coordination Chemistry Reviews, 2019 - Elsevier
The chromophores of several classes of well-established dyes, eg, indigo, 9, 10-
anthraquinones, formazanes, diketopyrrolopyrroles (DPPs), or certain azo compounds, are …

Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes

A Mandal, B Schwederski, J Fiedler, W Kaim… - Inorganic …, 2015 - ACS Publications
Redox series of the complexes [Ru (L)(L′) 2] n, L= 1, 5-diphenyl-3-(4-tolyl)-formazanate
and L′= 2, 4-pentanedionate (acac–), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine …

Noninnocence of indigo: dehydroindigo anions as bridging electron-donor ligands in diruthenium complexes

P Mondal, M Chatterjee, A Paretzki, K Beyer… - Inorganic …, 2016 - ACS Publications
Complexes of singly or doubly deprotonated indigo (H2Ind) with one or two [Ru (pap) 2] 2+
fragments (pap= 2-phenylazopyridine) have been characterized experimentally [molecular …

Questions of Noninnocence and Ease of Azo Reduction in Diruthenium Frameworks with a 1,8-Bis((E)-phenyldiazenyl)naphthalene-2,7-dioxido Bridge

FF Khan, J Klein, JL Priego, B Sarkar… - Inorganic …, 2018 - ACS Publications
Ligands containing the azo group are often used in various metal complexes owing to their
facile one-electron reduction, which in effect extends the means of degrading …

Counter-ligand control of the electronic structure in dinuclear copper-tetrakisguanidine complexes

A Ziesak, T Wesp, O Hübner, E Kaifer… - Dalton …, 2015 - pubs.rsc.org
The redox-active GFA (Guanidino-Functionalized Aromatic compound) 1, 4, 5, 8-tetrakis
(tetramethylguanidino)-naphthalene (6) is used to synthesize new dinuclear copper …

The Electron-Rich {Ru(acac)2} Directed Varying Configuration of the Deprotonated Indigo and Evidence for Its Bidirectional Noninnocence

P Mondal, A Das, GK Lahiri - Inorganic Chemistry, 2016 - ACS Publications
This article highlights the hitherto unexplored varying binding modes of the deprotonated
natural dye indigo (H2L) and its bidirectional noninnocent potential. The reaction of H2L with …

Noninnocently behaving bridging anions of the widely distributed antioxidant ellagic acid in diruthenium complexes

A Mandal, A Grupp, B Schwederski, W Kaim… - Inorganic …, 2015 - ACS Publications
Dinuclear compounds [L2Ru (μ-E) RuL2] n where L is acetylacetonate (acac–, 2, 4-
pentanedionate), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine (pap) and EH4 is ellagic …

Metal–metal bridging using the DPPP dye system: electronic configurations within multiple redox series

A Singha Hazari, A Mandal, K Beyer… - Inorganic …, 2017 - ACS Publications
Redox series [L n Ru (μ-DPPP) RuL n] k, H2DPPP= 2, 5-dihydro-3, 6-di-2-pyridylpyrrolo (3,
4-c) pyrrole-1, 4-dione and L= 2, 4-pentanedionato (acac–), 2, 2′-bipyridine (bpy), and 2 …

Redox‐Induced Oxidative C− C Bond Cleavage of 2, 2′‐Pyridil in Diruthenium Complexes

FF Khan, S Sobottka, B Sarkar… - Chemistry–A European …, 2019 - Wiley Online Library
In the recent years, there has been an emerging research interest in the domain of C− C
bond‐cleavage reactions. The present contribution deals with the redox‐mediated dioxygen …