s-Block metal catalysts for the hydroboration of unsaturated bonds
The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry
TX Gentner, RE Mulvey - Angewandte Chemie International …, 2021 - Wiley Online Library
Organolithium compounds have been at the forefront of synthetic chemistry for over a
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …
Recent advances in the catalytic hydroboration of carbonyl compounds
The chemoselective catalytic hydroboration of aldehydes and ketones has found
widespread applications in organic chemistry due to the synthetic utility of borate ester …
widespread applications in organic chemistry due to the synthetic utility of borate ester …
Hydrosilylation and hydroboration in a sustainable manner: from Earth-abundant catalysts to catalyst-free solutions
Hydroelementation enables a facile reduction or functionalization of several unsaturated
systems, and thus activation of such bonds like B–H and Si–H is a powerful synthetic tool …
systems, and thus activation of such bonds like B–H and Si–H is a powerful synthetic tool …
Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters
High performance biodegradable polymers (eg, aliphatic polyesters) that can display
properties that rival polyolefins are seen as future high demand materials for a variety of …
properties that rival polyolefins are seen as future high demand materials for a variety of …
N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes
Recent years have witnessed a significant growth in the area of low-valent main-group
compounds due to their potential to activate small molecules. However, there is a paucity of …
compounds due to their potential to activate small molecules. However, there is a paucity of …
Zirconium Complex as an Efficient Catalyst in the Hydroboration of Nitriles, Alkynes, and Carboxylic Esters: A Combined Experimental and Computational Study
We report the synthesis of a zirconium complex {κ2-[Ph2P (S) NCH2CH2N (CH2CH2) O] Zr
(C5H5) 2Cl}(2) supported by a flexible amidophosphinosulfide ligand [Ph2P (S) N (CH2) 2N …
(C5H5) 2Cl}(2) supported by a flexible amidophosphinosulfide ligand [Ph2P (S) N (CH2) 2N …
Application of an electrochemical microflow reactor for cyanosilylation: machine learning-assisted exploration of suitable reaction conditions for semi-large-scale …
Cyanosilylation of carbonyl compounds provides protected cyanohydrins, which can be
converted into many kinds of compounds such as amino alcohols, amides, esters, and …
converted into many kinds of compounds such as amino alcohols, amides, esters, and …
Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
W Wang, M Luo, W Yao, M Ma… - ACS Sustainable …, 2018 - ACS Publications
A simple catalyst-free and solvent-free method for the cyanosilylation of a variety of
aldehydes with trimethylsilyl cyanide as well as the Knoevenagel condensation reaction of …
aldehydes with trimethylsilyl cyanide as well as the Knoevenagel condensation reaction of …
O, N-Heterocyclic germylenes as efficient catalysts for hydroboration and cyanosilylation of benzaldehyde
KV Arsenyeva, KI Pashanova, OY Trofimova… - New Journal of …, 2021 - pubs.rsc.org
New monomeric O, N-heterocyclic germylene AdAPGe (1) based on 4, 6-di-tert-butyl-N-
adamantyl-o-aminophenol is synthesized and structurally characterized. Germylene 1 in the …
adamantyl-o-aminophenol is synthesized and structurally characterized. Germylene 1 in the …