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Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …
fuels have stimulated extensive research to identify new energy systems and economies that …
Surface chemistry of porphyrins and phthalocyanines
JM Gottfried - Surface Science Reports, 2015 - Elsevier
This review covers the surface chemistry of porphyrins, phthalocyanines, their metal
complexes, and related compounds, with particular focus on chemical reactions at …
complexes, and related compounds, with particular focus on chemical reactions at …
Driving the oxygen evolution reaction by nonlinear cooperativity in bimetallic coordination catalysts
Develo** efficient catalysts for electrolysis, in particular for the oxygen evolution in the
anodic half cell reaction, is an important challenge in energy conversion technologies. By …
anodic half cell reaction, is an important challenge in energy conversion technologies. By …
Metalloporphyrins: bioinspired oxidation catalysts
The utilization of metalloporphyrins as bioinspired oxidation catalysts is an evolving topic of
research. By understanding the cytochrome P-450 mechanism of action, chemists have …
research. By understanding the cytochrome P-450 mechanism of action, chemists have …
Mimicking enzymatic active sites on surfaces for energy conversion chemistry
Metal–organic supramolecular chemistry on surfaces has matured to a point where its
underlying growth mechanisms are well understood and structures of defined coordination …
underlying growth mechanisms are well understood and structures of defined coordination …
Probing molecular-scale catalytic interactions between oxygen and cobalt phthalocyanine using tip-enhanced Raman spectroscopy
Ultrahigh vacuum tip-enhanced Raman spectroscopy (UHV-TERS) is used to investigate
adsorption of molecular oxygen (O2) on cobalt (II) phthalocyanine (CoPc) supported on Ag …
adsorption of molecular oxygen (O2) on cobalt (II) phthalocyanine (CoPc) supported on Ag …
Single metal atom catalysts and ORR: H-bonding, solvation, and the elusive hydroperoxyl intermediate
The widely investigated oxygen reduction reaction (ORR) is well-known to proceed via two
competing routes, involving two or four electrons, and yielding different reaction products …
competing routes, involving two or four electrons, and yielding different reaction products …
Co (III), Co (II), Co (I): Tuning Single Cobalt Metal Atom Oxidation States in a 2D Coordination Network
It is shown that the self‐assembly of a surface‐confined metal–organic network such as
cobalt porphyrins on graphene is accompanied by the evolution of coordination‐dependent …
cobalt porphyrins on graphene is accompanied by the evolution of coordination‐dependent …
Direct quantitative identification of the “surface trans-effect”
The strong parallels between coordination chemistry and adsorption on metal surfaces, with
molecules and ligands forming local bonds to individual atoms within a metal surface, have …
molecules and ligands forming local bonds to individual atoms within a metal surface, have …
Tuning Surface Organic Structures by Small Gas Molecules through Catassembly and Coassembly
J Li, X Wang, Y He, Z Xu, X Li, H Pan… - The Journal of …, 2024 - ACS Publications
The field of molecular assembly has seen remarkable advancements across various
domains, such as materials science, nanotechnology, and biomedicine. Small gas …
domains, such as materials science, nanotechnology, and biomedicine. Small gas …