Transition-metal-catalyzed reductive amination employing hydrogen

T Irrgang, R Kempe - Chemical Reviews, 2020 - ACS Publications
The reductive amination, the reaction of an aldehyde or a ketone with ammonia or an amine
in the presence of a reducing agent and often a catalyst, is an important amine synthesis …

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

% V Bur index and steric maps: from predictive catalysis to machine learning

S Escayola, N Bahri-Laleh, A Poater - Chemical Society Reviews, 2024 - pubs.rsc.org
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …

Iron catalysis in reduction and hydrometalation reactions

D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …

Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Recent advances in homogeneous catalysts for the asymmetric hydrogenation of heteroarenes

AN Kim, BM Stoltz - ACS catalysis, 2020 - ACS Publications
The asymmetric hydrogenation of heteroarenes has recently emerged as an effective
strategy for the direct access to enantioenriched, saturated heterocycles. Although several …

Iron‐catalyzed α‐Alkylation of Ketones with Alcohols

S Elangovan, JB Sortais, M Beller… - Angewandte Chemie …, 2015 - Wiley Online Library
A general and benign iron‐catalyzed α‐alkylation reaction of ketones with primary alcohols
has been developed. The key to success of the reaction is the use of a Knölker‐type …

Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol

A Lator, S Gaillard, A Poater, JL Renaud - Organic letters, 2018 - ACS Publications
An iron (0) complex bearing a cyclopentadienone ligand catalyzed N-methylation and N-
ethylation of aryl and aliphatic amines with methanol or ethanol in mild and basic conditions …

C–N bond formation between alcohols and amines using an iron cyclopentadienone catalyst

AJ Rawlings, LJ Diorazio, M Wills - Organic letters, 2015 - ACS Publications
C–N Bond Formation between Alcohols and Amines Using an Iron Cyclopentadienone Catalyst |
Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters …

Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols

K Polidano, JMJ Williams, LC Morrill - ACS catalysis, 2019 - ACS Publications
Herein we report the iron-catalyzed β-C (sp3)-methylation of primary alcohols using
methanol as a C1 building block. This borrowing hydrogen approach employs a well …