Transition-metal-catalyzed reductive amination employing hydrogen
T Irrgang, R Kempe - Chemical Reviews, 2020 - ACS Publications
The reductive amination, the reaction of an aldehyde or a ketone with ammonia or an amine
in the presence of a reducing agent and often a catalyst, is an important amine synthesis …
in the presence of a reducing agent and often a catalyst, is an important amine synthesis …
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
% V Bur index and steric maps: from predictive catalysis to machine learning
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …
atoms or groups of atoms in molecules. They are important in determining the reactivity …
Iron catalysis in reduction and hydrometalation reactions
D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …
Iron catalysis in organic synthesis
I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …
June 2014 and represents a comprehensive update of a previous article published by Bolm …
Recent advances in homogeneous catalysts for the asymmetric hydrogenation of heteroarenes
AN Kim, BM Stoltz - ACS catalysis, 2020 - ACS Publications
The asymmetric hydrogenation of heteroarenes has recently emerged as an effective
strategy for the direct access to enantioenriched, saturated heterocycles. Although several …
strategy for the direct access to enantioenriched, saturated heterocycles. Although several …
Iron‐catalyzed α‐Alkylation of Ketones with Alcohols
S Elangovan, JB Sortais, M Beller… - Angewandte Chemie …, 2015 - Wiley Online Library
A general and benign iron‐catalyzed α‐alkylation reaction of ketones with primary alcohols
has been developed. The key to success of the reaction is the use of a Knölker‐type …
has been developed. The key to success of the reaction is the use of a Knölker‐type …
Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol
An iron (0) complex bearing a cyclopentadienone ligand catalyzed N-methylation and N-
ethylation of aryl and aliphatic amines with methanol or ethanol in mild and basic conditions …
ethylation of aryl and aliphatic amines with methanol or ethanol in mild and basic conditions …
C–N bond formation between alcohols and amines using an iron cyclopentadienone catalyst
AJ Rawlings, LJ Diorazio, M Wills - Organic letters, 2015 - ACS Publications
C–N Bond Formation between Alcohols and Amines Using an Iron Cyclopentadienone Catalyst |
Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters …
Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters …
Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols
K Polidano, JMJ Williams, LC Morrill - ACS catalysis, 2019 - ACS Publications
Herein we report the iron-catalyzed β-C (sp3)-methylation of primary alcohols using
methanol as a C1 building block. This borrowing hydrogen approach employs a well …
methanol as a C1 building block. This borrowing hydrogen approach employs a well …