% V Bur index and steric maps: from predictive catalysis to machine learning
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …
atoms or groups of atoms in molecules. They are important in determining the reactivity …
Transition-metal-catalyzed reductive amination employing hydrogen
T Irrgang, R Kempe - Chemical Reviews, 2020 - ACS Publications
The reductive amination, the reaction of an aldehyde or a ketone with ammonia or an amine
in the presence of a reducing agent and often a catalyst, is an important amine synthesis …
in the presence of a reducing agent and often a catalyst, is an important amine synthesis …
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Iron catalysis in reduction and hydrometalation reactions
D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …
Iron catalysis in organic synthesis
I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …
June 2014 and represents a comprehensive update of a previous article published by Bolm …
Recent advances in homogeneous catalysts for the asymmetric hydrogenation of heteroarenes
AN Kim, BM Stoltz - ACS catalysis, 2020 - ACS Publications
The asymmetric hydrogenation of heteroarenes has recently emerged as an effective
strategy for the direct access to enantioenriched, saturated heterocycles. Although several …
strategy for the direct access to enantioenriched, saturated heterocycles. Although several …
Iron‐catalyzed α‐Alkylation of Ketones with Alcohols
S Elangovan, JB Sortais, M Beller… - Angewandte Chemie …, 2015 - Wiley Online Library
A general and benign iron‐catalyzed α‐alkylation reaction of ketones with primary alcohols
has been developed. The key to success of the reaction is the use of a Knölker‐type …
has been developed. The key to success of the reaction is the use of a Knölker‐type …
Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol
An iron (0) complex bearing a cyclopentadienone ligand catalyzed N-methylation and N-
ethylation of aryl and aliphatic amines with methanol or ethanol in mild and basic conditions …
ethylation of aryl and aliphatic amines with methanol or ethanol in mild and basic conditions …
C–N bond formation between alcohols and amines using an iron cyclopentadienone catalyst
AJ Rawlings, LJ Diorazio, M Wills - Organic Letters, 2015 - ACS Publications
C–N Bond Formation between Alcohols and Amines Using an Iron Cyclopentadienone Catalyst
| Organic Letters Recently Viewedclose modal ACS ACS Publications C&EN CAS Find my …
| Organic Letters Recently Viewedclose modal ACS ACS Publications C&EN CAS Find my …
Iron-Catalyzed α-Alkylation of Ketones with Secondary Alcohols: Access to β-Disubstituted Carbonyl Compounds
An iron-catalyzed borrowing hydrogen strategy has been applied in the synthesis of β-
branched carbonyl compounds. Various secondary benzylic and aliphatic alcohols have …
branched carbonyl compounds. Various secondary benzylic and aliphatic alcohols have …