On the structural role of boron in borosilicate glasses

M Hubert, AJ Faber - … Chemistry of Glasses-European Journal of …, 2014 - ingentaconnect.com
The outstanding thermal, mechanical and optical properties of borosilicate glasses give
them significant advantages for applications where conventional soda–lime–silica glasses …

Glass as a state of matter—the “newer” glass families from organic, metallic, ionic to non-silicate oxide and non-oxide glasses

D Möncke, B Topper, AG Clare - Reviews in Mineralogy …, 2022 - pubs.geoscienceworld.org
OVERVIEW In theory, any molten material can form a glass when quenched fast enough.
Most natural glasses are based on silicates and for thousands of years only alkali/alkaline …

Zinc borate glasses: properties, structure and modelling of the composition-dependence of borate speciation

B Topper, D Möncke, RE Youngman, C Valvi… - Physical Chemistry …, 2023 - pubs.rsc.org
The short-range order of binary zinc borate glasses, xZnO–(1− x) B2O3, has been
quantitatively described as a function of ZnO content over the entire glass forming range for …

Three-coordinated boron-11 chemical shifts in borates

S Kroeker, JF Stebbins - Inorganic Chemistry, 2001 - ACS Publications
Despite the importance of 11B nuclear magnetic resonance (NMR) in structural studies of
borate glasses, no clear means of correlating NMR parameters with the number of …

Results on disordered materials from the GEneral Materials diffractometer, GEM, at ISIS

AC Hannon - Nuclear Instruments and Methods in Physics Research …, 2005 - Elsevier
The GEneral Materials diffractometer, GEM, at the ISIS Facility pulsed neutron source is the
most advanced materials neutron diffractometer in the world. A full description of GEM is …

BO3/BO4 Intermixing in Borosilicate Glass Networks Probed by Double-Quantum 11B NMR: What Factors Govern BO4–BO4 Formation?

P Lv, B Stevensson, Y Yu, T Wang… - The Journal of Physical …, 2023 - ACS Publications
We examine the borate group intermixing in a series of 25 borosilicate (BS) glasses from the
[0.5 M (2) O–0.5 Na2O]–B2O3–SiO2 systems with M={Li, K, Rb, Mg, Ca} along with ternary …

Transition and post-transition metal ions in borate glasses: Borate ligand speciation, cluster formation, and their effect on glass transition and mechanical properties

D Möncke, EI Kamitsos, D Palles, R Limbach… - The Journal of …, 2016 - pubs.aip.org
A series of transition and post-transition metal ion (Mn, Cu, Zn, Pb, Bi) binary borate glasses
was studied with special consideration of the cations impact on the borate structure, the …

Borate structures: crystalline and vitreous

AC Wright - Physics and Chemistry of Glasses-European …, 2010 - ingentaconnect.com
A comprehensive survey is presented of the structures of the crystalline phases formed in
M2O–B2O3 and MO–B2O3 glass forming systems, with particular reference to those aspects …

Understanding diffraction patterns of glassy, liquid and amorphous materials via persistent homology analyses

Y Onodera, S Kohara, S Tahara, A Masuno… - Journal of the Ceramic …, 2019 - jstage.jst.go.jp
The absence of translational symmetry, and the very much present complexity in the
structure of glassy, liquid, and amorphous materials make glass science a challenging field …

Boroxol Rings in Liquid and Vitreous from First Principles

G Ferlat, T Charpentier, AP Seitsonen, A Takada… - Physical review …, 2008 - APS
We investigate the structural and vibrational properties of glassy B 2 O 3 using first-
principles molecular dynamics simulations. In particular, we determine the boroxol rings …