Hydrofomylation is an important industrial process for aldehyde production which follows the
atom-economy principle. In this homogeneous process, the separation and subsequent …

In the last four decades, one of the most important advances in organometallic catalysis has
been the use of molecular catalysts in two-phase liquid-liquid systems, commonly known as …

Alkene hydroformylation is an extremely important industry process currently accomplished
via homogeneous catalysis. Heterogeneous hydroformylation is being avidly pursued as a …

Catalytic hydroformylation is an important reaction, widely studied by academics and
applied in the chemical industry, and it is a paradigmatic example of a chemical reaction that …

Biphasic catalysis enables the effective recycling of homogeneous catalysts by their
immobilization in an additional liquid phase immiscible with the products. The introduced …

We have developed a Keggin polyoxometalate (POM)‐based ionic‐liquid (IL)‐immobilizing
rhodium single‐atom Rh catalyst (MTOA) 5 [SiW11O39Rh](MOTA= methyltrioctylammonium …

Methods that form amines from feedstock chemicals are an important component of
industrial chemistry. Many methods for the synthesis of amines yield mixtures of primary …

Rh-based bimetallic catalysts are promising ligand-free heterogeneous catalysts for
hydroformylation reactions. It is important to understand the mechanism of this bimetallic …

Ethylene carbonate is a rather uncommon solvent in chemistry, but it can be used as a low-
viscosity, polar, aprotic solvent. Its most interesting feature is the melting point above room …

Water based biphasic hydroformylation assisted by cyclodextrins is known for enhanced
reaction rates in comparison to the non-assisted biphasic hydroformylation. In this paper, the …