Prediction of molecular properties and molecular spectroscopy with density functional theory: From fundamental theory to exchange-coupling

F Neese - Coordination Chemistry Reviews, 2009 - Elsevier
This review provides a detailed account of density functional theory (DFT) and its application
to the calculation of molecular properties of inorganic compounds. After introducing some …

The unique fold and lability of the [2Fe-2S] clusters of NEET proteins mediate their key functions in health and disease

O Karmi, HB Marjault, L Pesce, P Carloni… - JBIC Journal of …, 2018 - Springer
NEET proteins comprise a new class of [2Fe-2S] cluster proteins. In human, three genes
encode for NEET proteins: cisd1 encodes mitoNEET (mNT), cisd2 encodes the Nutrient …

Meeting the challenge of magnetic coupling in a triply-bridged chromium dimer: complementary broken-symmetry density functional theory and multireference density …

DA Pantazis - Journal of chemical theory and computation, 2019 - ACS Publications
Face-sharing octahedral dinuclear Cr (III) compounds with d3–d3 electronic configurations
represent nontrivial examples of electronic complexity, posing particular challenges for …

Broadly Applicable Z‐ and Diastereoselective Ring‐Opening/Cross‐Metathesis Catalyzed by a Dithiolate Ru Complex

MJ Koh, RKM Khan, S Torker… - Angewandte …, 2014 - Wiley Online Library
A broadly applicable Ru‐catalyzed protocol for Z‐selective ring‐opening/cross‐metathesis
(ROCM) is disclosed. In addition to reactions relating to terminal alkenes of different sizes …

Electronic structure investigation and parametrization of biologically relevant iron–sulfur clusters

ATP Carvalho, M Swart - Journal of chemical information and …, 2014 - ACS Publications
The application of classical molecular dynamics simulations to the study of metalloenzymes
has been hampered by the lack of suitable molecular mechanics force field parameters to …

Dynamical effects on the magnetic properties of dithiazolyl bistable materials

S Vela, M Deumal, M Shiga, JJ Novoa… - Chemical …, 2015 - pubs.rsc.org
The magnetic properties of molecule-based magnets are commonly rationalized by
considering only a single nuclear configuration of the system under study (usually an X-ray …

Accelerated Computer-Aided Screening of Optical Materials: Investigating the Potential of Δ-SCF Methods to Predict Emission Maxima of Large Dye Molecules

V Tripathy, AH Flood… - The Journal of Physical …, 2024 - ACS Publications
Accurate simulation of electronic excited states of large chromophores is often difficult due to
the computationally expensive nature of existing methods. Common approximations such as …

Magnetic interactions in the catalyst used by nature to split water: a DFT+ U multiscale study on the Mn4CaO5 core in photosystem II

D Bovi, D Narzi, L Guidoni - New Journal of Physics, 2014 - iopscience.iop.org
An important approach in the design of new environmentally friendly materials is
represented by the study of analogous systems already existing in nature. In the search for …

Magnetic coupling constants and vibrational frequencies by extended broken symmetry approach with hybrid functionals

D Bovi, L Guidoni - The Journal of Chemical Physics, 2012 - pubs.aip.org
The description of the electronic structure and magnetic properties of multi-centers transition
metal complexes, especially of mixed-valence compounds, still represents a challenge for …

Magnetostructural dynamics with the extended broken symmetry formalism: Antiferromagnetic [2Fe-2S] complexes

NN Nair, E Schreiner, R Pollet… - Journal of Chemical …, 2008 - ACS Publications
A general spin-projection framework is laid out which allows one to perform ab initio
molecular dynamics simulations of antiferromagnetically coupled spin dimers. The method …