Palladium catalysis has achieved the status of an indispensable tool for both common and
state-of-theart organic synthesis. Among basic types of palladium-catalyzed transformations …

Starting from the early 1990s, the chemistry of polyvalent iodine organic compounds has
experienced an explosive development. This surging interest in iodine compounds is mainly …

The recent groundbreaking developments in the application of diaryliodonium salts in cross‐
coupling reactions has brought this class of previously underdeveloped reagents to the …

The unique reactivity of hypervalent iodine reagents with Pd0 and PdII complexes has been
exploited for a variety of synthetically useful organic transformations. For example, IIII …

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This chapter focuses on recent developments in metal-free and metal-catalyzed arylations
with diaryliodonium salts (diaryl-λ 3-iodanes). Synthetic routes to diaryliodonium salts are …

A novel chelate-controlled intermolecular oxidative Heck reaction is reported that proceeds
with a wide range of nonresonance stabilized α-olefin substrates and organoboron reagents …

Here, we report the method for copper‐catalyzed N‐arylation of diverse oxadiazolones by
diaryliodonium salts under mild conditions in high yields (up to 92%) using available CuI as …

A new method for copper-catalyzed P–C bond formation through reaction of phosphorus
nucleophiles with diaryliodonium salts at room temperature is described. Most target …

This review gives an overview of the use of unusual diazonium and iodonium salts as
electrophiles for the Suzuki–Miyaura reaction. The discussion mainly focuses, with a critical …