3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

C H Bond Activation by f‐Block Complexes

PL Arnold, MW McMullon, J Rieb… - Angewandte Chemie …, 2015 - Wiley Online Library
Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

Transmetalation of unsaturated carbon nucleophiles from boron-containing species to the mid to late d-block metals of relevance to catalytic C− X coupling reactions …

DV Partyka - Chemical Reviews, 2011 - ACS Publications
Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Recent progress in rare-earth metal-catalyzed sp 2 and sp 3 C–H functionalization to construct C–C and C–heteroelement bonds

K Seth - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
C–H functionalization is a fundamentally important organic transformation to access C–C
and C–heteroatom bonds in a common and/or complex molecular set-up during the …

Rare-earth metal and actinide organoimide chemistry

D Schädle, R Anwander - Chemical Society Reviews, 2019 - pubs.rsc.org
The chemistry of actinide (An) and rare-earth metal (Ln and group 3) complexes featuring
multiple bonding interactions with main-group fragments has witnessed an enormous …

Metal-catalyzed 1, 3-dipolar cycloaddition reactions of nitrile oxides

S Roscales, J Plumet - Organic & Biomolecular Chemistry, 2018 - pubs.rsc.org
In the present review advances in the metal-catalyzed 1, 3-dipolar cycloaddition reactions of
nitrile oxides, mainly in the last decade, will be presented and discussed. An overview on …

Cyclometalative C–H bond activation in rare earth and actinide metal complexes

KRD Johnson, PG Hayes - Chemical Society Reviews, 2013 - pubs.rsc.org
Cyclometalative C–H bond activation is a process that is commonly encountered in the field
of organometallic chemistry. In rare earth and actinide complexes, ligand cyclometalation is …

Terminal dysprosium and holmium organoimides

TE Rieser, D Schädle, C Maichle-Mössmer… - Chemical …, 2024 - pubs.rsc.org
Terminal rare-earth-metal imide complexes TptBu, MeLn (NC6H3iPr2-2, 6)(dmap) of the mid-
late rare-earth elements dysprosium and holmium were synthesized via double methane …

Open-Shell Early Lanthanide Terminal Imides

TE Rieser, R Thim-Spöring, D Schädle… - Journal of the …, 2022 - ACS Publications
Group 3-and 4f-element organometallic chemistry and reactivity are decisively driven by the
rare-earth-metal/lanthanide (Ln) ion size and associated electronegativity/ionicity/Lewis …

A scandium terminal imido complex: synthesis, structure and DFT studies

E Lu, Y Li, Y Chen - Chemical communications, 2010 - pubs.rsc.org
The first rare earth metal terminal imido complex has been isolated and structurally
characterized. The complex has an extremely short M–N bond length and a nearly linear M …