Roaming signature in photodissociation of carbonyl compounds

KC Lin, PY Tsai, MH Chao, M Nakamura… - … Reviews in Physical …, 2018 - Taylor & Francis
An alternative to the transition state (TS) pathway, the roaming route, which bypasses the
minimum energy path but produces the same molecular products, was recently found in …

Photodissociation dynamics of OCS near 214 nm using ion imaging

W Wei, CJ Wallace, GC McBane… - The Journal of chemical …, 2016 - pubs.aip.org
The OCS photodissociation dynamics of the dominant S (1 D 2) channel near 214 nm have
been studied using velocity map ion imaging. We report a CO vibrational branching ratio of …

Dynamics and vector correlations of vacuum ultraviolet (VUV) photodissociation of CO 2 at 155 nm

E Sakkoula, G Sharma, X Wang, SW North… - Physical Chemistry …, 2022 - pubs.rsc.org
In this work, the CO2 Vacuum Ultraviolet (VUV) photodissociation dynamics of the dominant
O (1D) channel near 155 nm have been studied using Velocity Map Imaging (VMI) …

New insights into the photodissociation of methyl iodide at 193 nm: stereodynamics and product branching ratios

SM Poullain, MG González, PC Samartzis… - Physical Chemistry …, 2015 - pubs.rsc.org
The stereodynamics of methyl iodide photodissociation after excitation at 193 nm has been
studied using a combination of slice imaging and resonance enhanced multiphoton …

Stereodynamics of multistate roaming

MP Grubb, ML Warter, SW North - Physical Chemistry Chemical …, 2012 - pubs.rsc.org
We present a molecular level description of NO3→ NO+ O2 photodissociation for both of the
experimentally observed reaction pathways using the results of ion imaging experiments …

Evidence for lambda doublet propensity in the UV photodissociation of ozone

CE Gunthardt, MN Aardema, GE Hall… - The Journal of Chemical …, 2019 - pubs.aip.org
The photodissociation of O 3 at 266 nm has been studied using velocity mapped ion
imaging. We report temperature-dependent vector correlations for the O 2 (a 1 Δ g, v= 0, j …

Stereodynamics of the Photodissociation of Nitromethane at 193 nm: Unravelling the Dissociation Mechanism

JD Rodríguez, MG González… - The Journal of …, 2013 - ACS Publications
The photodissociation of nitromethane at 193 nm is reviewed in terms of new
stereodynamical information provided by the measurement of the first four Dixon's bipolar …

Imaging the stereodynamics of methyl iodide photodissociation in the second absorption band: fragment polarization and the interplay between direct and …

MG González, JD Rodríguez, L Rubio-Lago… - Physical Chemistry …, 2014 - pubs.rsc.org
The stereochemistry of methyl iodide photodissociation in the onset of the second
absorption B-band has been studied using slice imaging of the CH3 (ν= 0) and I*(2P1/2) …

A method of extracting speed-dependent vector correlations from 2+ 1 REMPI ion images

W Wei, CJ Wallace, MP Grubb, SW North - The Journal of Chemical …, 2017 - pubs.aip.org
We present analytical expressions for extracting Dixon's bipolar moments in the semi-
classical limit from experimental anisotropy parameters of sliced or reconstructed non-sliced …

Primary and Secondary Loss of CO and NO Ligands in the Ultraviolet Photodissociation of the Heteroleptic Co(CO)3NO Complex

H Nakata, K Nagamori, M Haze… - The Journal of …, 2020 - ACS Publications
The photodissociation dynamics of the heteroleptic Co (CO) 3NO complex were investigated
in the metal-to-carbonyl (CO) ligand charge-transfer band to compare the reactivity of the CO …