Intermolecular dynamics, interactions, and solvation in ionic liquids

EW Castner Jr, JF Wishart… - Accounts of chemical …, 2007‏ - ACS Publications
Ionic liquids can simultaneously assume multiple solvent roles, because they are strongly
polar and polarizable solvents and binary solutions and frequently contain very hydrophobic …

Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect

Z Hu, CJ Margulis - Accounts of chemical research, 2007‏ - ACS Publications
Ionic liquids (ILs) have recently attracted significant attention from academic and industrial
sources. This is because, while their vapor pressures are negligible, many of them are …

Application of ionic liquids to the electrodeposition of metals

AP Abbott, KJ McKenzie - Physical Chemistry Chemical Physics, 2006‏ - pubs.rsc.org
The electrodeposition of most of technologically important metals has been shown to be
possible from a wide range of room temperature molten salts, more commonly known today …

Temperature and composition dependence of the density and viscosity of binary mixtures of water+ ionic liquid

H Rodriguez, JF Brennecke - Journal of Chemical & Engineering …, 2006‏ - ACS Publications
Density and viscosity were determined for binary mixtures of water and three ionic liquids: 1-
ethyl-3-methylimidazolium ethylsulfate, 1-ethyl-3-methylimidazolium trifluoroacetate, and 1 …

Physico-chemical processes in imidazolium ionic liquids

J Dupont, PAZ Suarez - Physical Chemistry Chemical Physics, 2006‏ - pubs.rsc.org
Among the various properties exhibited by ionic liquids (ILs)—especially those based on the
imidazolium cation—their inherent ionic patterns, very low vapour pressure and pronounced …

Effect of water and organic solvents on the ionic dissociation of ionic liquids

W Li, Z Zhang, B Han, S Hu, Y **e… - The Journal of Physical …, 2007‏ - ACS Publications
The effect of water and several organic solvents on the density, viscosity, and conductivity of
ionic liquids (ILs) 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-n …

Dynamic stokes shift and excitation wavelength dependent fluorescence of dipolar molecules in room temperature ionic liquids

A Samanta - The Journal of Physical Chemistry B, 2006‏ - ACS Publications
Room temperature ionic liquids (RTILs) are viscous media consisting entirely of ions.
Because of the complex nature of various interactions in these media, the solvent properties …

Solvation and rotational dynamics of coumarin 153 in ionic liquids: Comparisons to conventional solvents

H **, GA Baker, S Arzhantsev, J Dong… - The journal of …, 2007‏ - ACS Publications
Steady-state and time-resolved emission spectroscopy with 25 ps resolution are used to
measure equilibrium and dynamic aspects of the solvation of coumarin 153 (C153) in a …

Measurements of the complete solvation response in ionic liquids

S Arzhantsev, H **, GA Baker… - The Journal of Physical …, 2007‏ - ACS Publications
Dynamic Stokes shift measurements of the solvatochromic probe trans-4-dimethylamino-4 '-
cyanostilbene were used to measure the solvation response of five imidazolium and one …

Fluorescence probing of temperature-dependent dynamics and friction in ionic liquid local environments

AM Funston, TA Fadeeva, JF Wishart… - The Journal of …, 2007‏ - ACS Publications
The solvation dynamics and local orientational friction for a series of four ionic liquids have
been probed using coumarin 153 (C153) as a function of temperature. These ionic liquids …