Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …

Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …

Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

The color change dark‐red⇌ colorless accompanies the transition of [Fe (l‐propyltetrazole)
6](BF4) 2 from the low‐spin state to the metastable high‐spin state. These states in this …

In this chapter an outline is presented of the principal features of electronic spin crossover.
The development of the subject is traced and the various modes of manifestation of spin …

In the present article we discuss the cooperative nature of the spin crossover phenomenon
in iron (II) complexes, providing a perspective of the state of the art in this area. The first …

This article reviews the most relevant chemical and structural aspects that influence the spin-
crossover phenomenon (SCO). Special attention is focussed on the recent development of …

The compound [Fe (tvp) 2 (NCS) 2]⋅ CH3OH, where tvp is 1, 2-di-(4-pyridyl)-ethylene, has
been synthesized and characterized by x-ray single-crystal diffraction. It consists of two …

One of the most important trends in the spin crossover (SCO) field is focused on the
synthesis of new molecule-based functional materials in which the SCO properties may be …

Valence tautomerism (VT) involves a reversible stimulated intramolecular electron transfer
between a redox-active ligand and redox-active metal. Bis (dioxolene)-bridged dinuclear …