Artificial photosynthesis: opportunities and challenges of molecular catalysts
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …
However, the field of molecular catalysis for AP has gradually declined in recent years …
[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …
challenges of the 21st century. Currently, the major part of the global energy supply is …
Copper–oxygen complexes revisited: structures, spectroscopy, and reactivity
CE Elwell, NL Gagnon, BD Neisen, D Dhar… - Chemical …, 2017 - ACS Publications
A longstanding research goal has been to understand the nature and role of copper–oxygen
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …
[HTML][HTML] Sacrificial electron donor reagents for solar fuel production
Y Pellegrin, F Odobel - Comptes Rendus Chimie, 2017 - Elsevier
Although justly considered as a cumbersome component in artificial photosystems, these
simple molecules are a “necessary evil” to drive photo-induced reactions aiming at …
simple molecules are a “necessary evil” to drive photo-induced reactions aiming at …
Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
Molecular chromophore–catalyst assemblies for solar fuel applications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
Identifying intermediates in electrocatalytic water oxidation with a manganese corrole complex
X Li, XP Zhang, M Guo, B Lv, K Guo, X **… - Journal of the …, 2021 - ACS Publications
Water nucleophilic attack (WNA) on high-valent terminal Mn-oxo species is proposed for O–
O bond formation in natural and artificial water oxidation. Herein, we report an …
O bond formation in natural and artificial water oxidation. Herein, we report an …
Finding the way to solar fuels with dye-sensitized photoelectrosynthesis cells
The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap,
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …