A comprehensive electron wavefunction analysis toolbox for chemists, Multiwfn

T Lu - The Journal of Chemical Physics, 2024 - pubs.aip.org
Analysis of electron wavefunction is a key component of quantum chemistry investigations
and is indispensable for the practical research of many chemical problems. After more than …

From NWChem to NWChemEx: Evolving with the computational chemistry landscape

K Kowalski, R Bair, NP Bauman, JS Boschen… - Chemical …, 2021 - ACS Publications
Since the advent of the first computers, chemists have been at the forefront of using
computers to understand and solve complex chemical problems. As the hardware and …

The versatility of the Cholesky decomposition in electronic structure theory

TB Pedersen, S Lehtola… - Wiley Interdisciplinary …, 2024 - Wiley Online Library
The resolution‐of‐the‐identity (RI) or density fitting (DF) approximation for the electron
repulsion integrals (ERIs) has become a standard component of accelerated and reduced …

How to VPT2: Accurate and intuitive simulations of CH stretching infrared spectra using VPT2+ K with large effective Hamiltonian resonance treatments

PR Franke, JF Stanton… - The Journal of Physical …, 2021 - ACS Publications
This article primarily discusses the utility of vibrational perturbation theory for the prediction
of X–H stretching vibrations with particular focus on the specific variant, second-order …

On the origin and nature of internal methyl rotation barriers: An information-theoretic approach study

K Wang, X He, C Rong, A Zhong, S Liu… - Theoretical Chemistry …, 2022 - Springer
Internal methyl rotation is a ubiquitous phenomenon in chemistry and could find ample
implications in other disciplines, where structure, reactivity, and function properties are …

A perspective on sustainable computational chemistry software development and integration

R Di Felice, ML Mayes, RM Richard… - Journal of chemical …, 2023 - ACS Publications
The power of quantum chemistry to predict the ground and excited state properties of
complex chemical systems has driven the development of computational quantum chemistry …

Reference energies for intramolecular charge-transfer excitations

PF Loos, M Comin, X Blase… - Journal of Chemical …, 2021 - ACS Publications
With the aim of completing our previous efforts devoted to local and Rydberg transitions in
organic compounds, we provide a series of highly accurate vertical transition energies for …

Comparing Self-Consistent GW and Vertex-Corrected G0W0 (G0W0Γ) Accuracy for Molecular Ionization Potentials

M Wen, V Abraham, G Harsha, A Shee… - Journal of Chemical …, 2024 - ACS Publications
We test the performance of self-consistent GW and several representative implementations
of vertex-corrected G 0 W 0 (G 0 W 0Γ). These approaches are tested on benchmark data …

Heptazine, cyclazine, and related compounds: Chemically-accurate estimates of the inverted singlet–triplet gap

PF Loos, F Lipparini, D Jacquemin - The Journal of Physical …, 2023 - ACS Publications
Molecules that violate Hund's rule and exhibit an inverted gap between the lowest singlet S1
and triplet T1 excited states have attracted considerable attention due to their potential …

The GW miracle in many-body perturbation theory for the ionization potential of molecules

F Bruneval, N Dattani, MJ van Setten - Frontiers in chemistry, 2021 - frontiersin.org
We use the GW100 benchmark set to systematically judge the quality of several perturbation
theories against high-level quantum chemistry methods. First of all, we revisit the reference …