Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

We report herein a simple, metal-and additive-free, photoinduced borylation of haloarenes,
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …

A pyridine-catalyzed transition-metal-free borylation reaction of haloarenes has been
developed based on the selective cross-coupling of an aryl radical and a pyridine-stabilized …

This perspective gives an overview on recent findings in the emerging area of C-radical
borylation using diborons as radical trap** reagents. Aryl, vinyl and alkyl boronic esters …

A Ni-catalyzed borylation via C–F activation is described. This protocol is distinguished by a
wide scope, including unactivated fluoroarenes, without compromising its efficiency and …

A highly selective and general photocatalytic C–F borylation protocol that employs a
rhodium biphenyl complex as a triplet sensitizer and the nickel catalyst [Ni (IMes) 2](IMes= 1 …

The preparation of arylboronates from unactivated aryl chlorides in a transition-metal-free
manner is rather challenging. There are only few examples to achieve this goal by using …

The [Ni (IMes) 2]-catalyzed transformation of fluoroarenes into arylboronic acid pinacol
esters via C–F bond activation and transmetalation with bis (pinacolato) diboron (B2pin2) is …