Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Nanoarchitectonics of metallene materials for electrocatalysis

B Jiang, Y Guo, F Sun, S Wang, Y Kang, X Xu, J Zhao… - ACS …, 2023 - ACS Publications
Controlling the synthesis of metal nanostructures is one approach for catalyst engineering
and performance optimization in electrocatalysis. As an emerging class of unconventional …

Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation

J Kang, X Qiu, Q Hu, J Zhong, X Gao, R Huang… - Nature Catalysis, 2021 - nature.com
Monolayer materials are endowed with an additional degree of freedom to modulate
electronic structures and catalytic performances. Here, we report a direct synthesis of …

In-plane strain engineering in ultrathin noble metal nanosheets boosts the intrinsic electrocatalytic hydrogen evolution activity

G Wu, X Han, J Cai, P Yin, P Cui, X Zheng, H Li… - Nature …, 2022 - nature.com
Strain has been shown to modulate the electronic structure of noble metal nanomaterials
and alter their catalytic performances. Since strain is spatially dependent, it is challenging to …

Emerging beyond-graphene elemental 2D materials for energy and catalysis applications

FR Fan, R Wang, H Zhang, W Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Elemental two-dimensional (2D) materials have emerged as promising candidates for
energy and catalysis applications due to their unique physical, chemical, and electronic …

Metallenes as functional materials in electrocatalysis

P Prabhu, JM Lee - Chemical Society Reviews, 2021 - pubs.rsc.org
Metallenes, atomically thin layers composed primarily of under-coordinated metal atoms,
have emerged as the newest members in the family of 2D nanomaterials. Furthermore, the …

Electronic modulation of non‐van der Waals 2D electrocatalysts for efficient energy conversion

H Wang, J Chen, Y Lin, X Wang, J Li, Y Li… - Advanced …, 2021 - Wiley Online Library
The exploration of efficient electrocatalysts for energy conversion is important for green
energy development. Owing to their high surface areas and unusual electronic structure, 2D …

Noble-metal nanocrystals with controlled shapes for catalytic and electrocatalytic applications

Y Shi, Z Lyu, M Zhao, R Chen, QN Nguyen… - Chemical …, 2020 - ACS Publications
The successful synthesis of noble-metal nanocrystals with controlled shapes offers many
opportunities to not only maneuver their physicochemical properties but also optimize their …

Defect engineering of two-dimensional transition-metal dichalcogenides: applications, challenges, and opportunities

Q Liang, Q Zhang, X Zhao, M Liu, ATS Wee - ACS nano, 2021 - ACS Publications
Atomic defects, being the most prevalent zero-dimensional topological defects, are
ubiquitous in a wide range of 2D transition-metal dichalcogenides (TMDs). They could be …

Metallic nanostructures with low dimensionality for electrochemical water splitting

L Li, P Wang, Q Shao, X Huang - Chemical Society Reviews, 2020 - pubs.rsc.org
Metallic nanostructures with low dimensionality (one-dimension and two-dimension)
possess unique structural characteristics and distinctive electronic and physicochemical …