Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented …
The stabilization and isolation of highly reactive species has long been the subject of
chemical research. This review will focus on a large and important class of reactive species …
chemical research. This review will focus on a large and important class of reactive species …
Group 14 hydrides with low valent elements for activation of small molecules
Transition metal compounds are well known as activators of small molecules, and they serve
as efficient catalysts for a variety of homogeneous and heterogeneous transformations. In …
as efficient catalysts for a variety of homogeneous and heterogeneous transformations. In …
Interstellar molecules: guides for new chemistry
Interstellar space is among the most remarkable chemical laboratories in the universe. The
existence of many unstable species with low-valent main group elements in the interstellar …
existence of many unstable species with low-valent main group elements in the interstellar …
Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH 3, N 2 H 4, H 2 O, H 2)
M Auer, J Bolten, K Eichele, H Schubert… - Chemical …, 2023 - pubs.rsc.org
Halide abstraction from tetrylidene complexes [TbbE (Br) IrH (PMe3) 3][E= Ge (1), Sn (2)]
and [Ar* E (Cl) IrH (PMe3) 3] gives the salts [TbbEIrH (PMe3) 3][BArF4][E= Ge (3), Sn (4)] …
and [Ar* E (Cl) IrH (PMe3) 3] gives the salts [TbbEIrH (PMe3) 3][BArF4][E= Ge (3), Sn (4)] …
Synthesis and Reactivity of a Zinc Diazoalkyl Complex:[3+ 2] Cycloaddition Reaction with Carbon Monoxide
This work reports the synthesis, characterization, and reactivity of the first example of a well‐
defined zinc α‐diazoalkyl complex. Treatment of zinc (I)‐zinc (I) bonded compound L2Zn2 …
defined zinc α‐diazoalkyl complex. Treatment of zinc (I)‐zinc (I) bonded compound L2Zn2 …
Synthesis of Si (IV)-and Ge (II)-Substituted Amines, Hydrazone, and Hydrazine from Hypersilyl Germylene
This study investigates the reactivity of a hypersilyl germylene [PhC (N t Bu) 2GeSi (SiMe3)
3](1) with various organic compounds including azides, diazoalkanes, 1, 2 …
3](1) with various organic compounds including azides, diazoalkanes, 1, 2 …
Reactivity of germanium (II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl …
A Jana, HW Roesky, C Schulzke - Dalton Transactions, 2010 - pubs.rsc.org
The reactions of stable β-diketiminate germanium (II) hydride LGeH (1)[L= HC (CMeNAr) 2,
Ar= 2, 6-iPr2C6H3] with nitrous oxide, trimethylsilyl azide, ketones, and alkynes are …
Ar= 2, 6-iPr2C6H3] with nitrous oxide, trimethylsilyl azide, ketones, and alkynes are …
Formation of Formic Acid Derivatives through Activation and Hydroboration of CO2 by Low-Valent Group 14 (Si, Ge, Sn, Pb) Catalysts
The chemistry of low-valent main group elements has attracted much attention in the past
decade. These species are relevant because they have been able to mimic transition metal …
decade. These species are relevant because they have been able to mimic transition metal …
Synthesis, characterization, and reactivity of an N-heterocyclic germanium (II) hydride: Reversible hydrogermylation of a phosphaalkyne
SL Choong, WD Woodul, C Schenk, A Stasch… - …, 2011 - ACS Publications
The β-diketiminato germanium (II) chloride complex [(Bu t MesNacnac) GeCl](Bu t
MesNacnac=[{N (Mes) C (But)} 2CH]−, Mes= mesityl) has been prepared and …
MesNacnac=[{N (Mes) C (But)} 2CH]−, Mes= mesityl) has been prepared and …