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Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …
Atomically tailored gold nanoclusters for catalytic application
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …
have significantly broadened the accessible sizes and structures. Such particles are well …
A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation
Single Pt atom catalysts are key targets because a high exposure of Pt substantially
enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active …
enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active …
Theoretical advances in understanding and designing the active sites for hydrogen evolution reaction
As a fundamental step of water splitting and a step** stone toward exploring other
multielectron transfer processes, the electrocatalytic hydrogen evolution reaction (HER) is …
multielectron transfer processes, the electrocatalytic hydrogen evolution reaction (HER) is …
Interplay of kernel shape and surface structure for NIR luminescence in atomically precise gold nanorods
XK Wan, XS Han, ZJ Guan, WQ Shi, JJ Li… - Nature …, 2024 - nature.com
It is challenging to attain strong near-infrared (NIR) emissive gold nanoclusters. Here we
show a rod-shaped cluster with the composition of [Au28 (p-MBT) 14 (Hdppa) 3](SO3CF3) 2 …
show a rod-shaped cluster with the composition of [Au28 (p-MBT) 14 (Hdppa) 3](SO3CF3) 2 …
Atomically precise metal nanoclusters: stable sizes and optical properties
R ** - Nanoscale, 2015 - pubs.rsc.org
Controlling nanoparticles with atomic precision has long been a major dream of
nanochemists. Breakthroughs have been made in the case of gold nanoparticles, at least for …
nanochemists. Breakthroughs have been made in the case of gold nanoparticles, at least for …
Structural isomerism in gold nanoparticles revealed by X-ray crystallography
Revealing structural isomerism in nanoparticles using single-crystal X-ray crystallography
remains a largely unresolved task, although it has been theoretically predicted with some …
remains a largely unresolved task, although it has been theoretically predicted with some …
A critical size for emergence of nonbulk electronic and geometric structures in dodecanethiolate-protected Au clusters
Y Negishi, T Nakazaki, S Malola… - Journal of the …, 2015 - ACS Publications
We report on how the transition from the bulk structure to the cluster-specific structure occurs
in n-dodecanethiolate-protected gold clusters, Au n (SC12) m. To elucidate this transition …
in n-dodecanethiolate-protected gold clusters, Au n (SC12) m. To elucidate this transition …
Precise synthesis, functionalization and application of thiolate-protected gold clusters
Thiolate-protected gold clusters (Au n (SR) m) have received significant attention as new
functional nanomaterials because they exhibit size-specific physical and chemical …
functional nanomaterials because they exhibit size-specific physical and chemical …
Isomerism in Au28(SR)20 Nanocluster and Stable Structures
Understanding the isomerism phenomenon at the nanoscale is a challenging task because
of the prerequisites of precise composition and structural information on nanoparticles …
of the prerequisites of precise composition and structural information on nanoparticles …