Conspectus Migratory cross-coupling via metal migration is a process of significant
academic and industrial interest. It provides an attractive alternative for the selective …

Herein, we report a Ni-catalyzed C (sp2)–H hydroxylation of aryl bromides with N2O as an
oxygen-atom donor. The reaction is enabled by a 1, 4-Ni translocation that results in …

Transition metal‐catalyzed direct decarboxylative transformations of aromatic carboxylic
acids usually require high temperatures, which limit the substrate's scope, especially for late …

Selective functionalization of ubiquitous C–H bonds based on 1, n-metal migration provides
an attractive and sustainable route to access complex molecules from readily available …

Abstract “Through space” metal/hydrogen shift constitutes one of the efficient elementary
step in organometallic chemistry to achieve selective remote C− H bond functionalization …

Catalytic reactions involving 1, n-metal migration from carbon to carbon enable a
nonclassical way of constructing organic molecular skeletons, rapidly providing complex …

Low‐valent chromium catalysts are cheap and less toxic compared to other transition metal
catalysts. Here in, we reported a ligand‐free chromium (III)‐catalyzed manganese reductive …

Transition-metal-catalyzed hydroarylation of unactivated alkenes via metal hydride
hydrogen atom transfer (MHAT) is an attractive approach for the construction of C (sp2)–C …

Aromatic aldehydes are the most fundamentally important compounds used in organic
synthesis. The development of new synthetic methods for introduction of a formyl group into …

We describe herein a novel, general, and robust approach to structurally diversified alkenyl
nitriles through a Rh-catalyzed cyano transfer reaction between alkynyl-malononitrile …