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Metabolic engineering and synthetic biology for isoprenoid production in Escherichia coli and Saccharomyces cerevisiae
Isoprenoids, often called terpenoids, are the most abundant and highly diverse family of
natural organic compounds. In plants, they play a distinct role in the form of photosynthetic …
natural organic compounds. In plants, they play a distinct role in the form of photosynthetic …
Engineering terpene synthases and their substrates for the biocatalytic production of terpene natural products and analogues
LA Johnson, RK Allemann - Chemical Communications, 2025 - pubs.rsc.org
Terpene synthases produce a wide number of hydrocarbon skeletons by controlling
intramolecular rearrangements of allylic pyrophosphate subtrates via reactive carbocation …
intramolecular rearrangements of allylic pyrophosphate subtrates via reactive carbocation …
Redesigning the molecular choreography to prevent hydroxylation in germacradien-11-ol synthase catalysis
Natural sesquiterpene synthases have evolved to make complex terpenoids by quenching
reactive carbocations either by proton transfer or by hydroxylation (water capture) …
reactive carbocations either by proton transfer or by hydroxylation (water capture) …
Nucleophilic Water Capture or Proton Loss: Single Amino Acid Switch Converts δ‐Cadinene Synthase into Germacradien‐4‐ol Synthase
M Loizzi, V González, DJ Miller, RK Allemann - ChemBioChem, 2018 - Wiley Online Library
Abstract δ‐Cadinene synthase is a sesquiterpene cyclase that utilises the universal achiral
precursor farnesyl diphosphate (FDP) to generate predominantly the bicyclic sesquiterpene …
precursor farnesyl diphosphate (FDP) to generate predominantly the bicyclic sesquiterpene …
Enhancing epi‐cedrol production in Escherichia coli by fusion expression of farnesyl pyrophosphate synthase and epi‐cedrol synthase
Terpene synthase catalyses acyclic diphosphate farnesyl diphosphate into desired
sesquiterpenes. In this study, a fusion enzyme was constructed by linking Santalum album …
sesquiterpenes. In this study, a fusion enzyme was constructed by linking Santalum album …
[كتاب][B] Organic Reaction Mechanisms: 2013
AC Knipe, MG Moloney - 2016 - Wiley Online Library
The present volume, the forty-ninth in the series, surveys research on organic reaction
mechanisms described in the available literature dated 2013. In order to limit the size of the …
mechanisms described in the available literature dated 2013. In order to limit the size of the …
Retracted Article: Synthesis of deuterated isopentyl pyrophosphates for chemo-enzymatic labelling methods: GC-EI-MS based 1, 2-hydride shift in epicedrol …
MS Said, GR Navale, JM Gajbhiye, SS Shinde - RSC advances, 2019 - pubs.rsc.org
A sesquiterpene epicedrol cyclase mechanism was elucidated based on the gas
chromatography coupled to electron impact mass spectrometry fragmentation data of …
chromatography coupled to electron impact mass spectrometry fragmentation data of …
Carbocations
This chapter reviews the use of carbocations in synthetic chemistry. This includes surveys of
new methods of generating carbocations, evaluation of their reactivities, and their use in …
new methods of generating carbocations, evaluation of their reactivities, and their use in …
Improved production of epi-cedrol and santalene by fusion protein expression: Stability study and cyclization mechanism of epi-cedrol biosynthesis
GR Navale - 2021 - dspace.ncl.res.in
A wide range of secondary metabolites are produced by living organisms such as plants,
bacteria and fungi as a part of their defense system against herbivores, pests and pathogens …
bacteria and fungi as a part of their defense system against herbivores, pests and pathogens …