Borates: A rich source for optical materials

M Mutailipu, KR Poeppelmeier, S Pan - Chemical Reviews, 2020 - ACS Publications
The primary goal of this review is to present a clear chemical perspective of borates in order
to stimulate and facilitate the discovery of new borate-based optical materials. These …

Energy–structure–property relationships in uranium metal–organic frameworks

SL Hanna, OK Farha - Chemical Science, 2023 - pubs.rsc.org
Located at the foot of the periodic table, uranium is a relatively underexplored element
possessing rich chemistry. In addition to its high relevance to nuclear power, uranium shows …

Emergence of uranium as a distinct metal center for building intrinsic X‐ray scintillators

Y Wang, X Yin, W Liu, J **e, J Chen… - Angewandte …, 2018 - Wiley Online Library
The combination of high atomic number and high oxidation state in UVI materials gives rise
to both high X‐ray attenuation efficiency and intense green luminescence originating from …

Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications

S Zhao, P Gong, L Bai, X Xu, S Zhang, Z Sun… - Nature …, 2014 - nature.com
Nonlinear optical (NLO) materials are of great importance in laser science and technology,
as they can expand the wavelength range provided by common laser sources. Few NLO …

BiFSeO3: An Excellent SHG Material Designed by Aliovalent Substitution

ML Liang, CL Hu, F Kong, JG Mao - Journal of the American …, 2016 - ACS Publications
The first bismuth selenite fluoride, BiFSeO3, was obtained by aliovalent substitution of 2D
BiOIO3. Its structure features a 3D network composed of 1D [BiF] 2+ chains interconnected …

Differentiating between trivalent lanthanides and actinides

MJ Polinski, DJ Grant, S Wang… - Journal of the …, 2012 - ACS Publications
The reactions of LnCl3 with molten boric acid result in the formation of Ln [B4O6 (OH)
2Cl](Ln= La–Nd), Ln4 [B18O25 (OH) 13Cl3](Ln= Sm, Eu), or Ln [B6O9 (OH) 3](Ln= Y, Eu …

MOFs of Uranium and the Actinides

J Su, J Chen - Lanthanide Metal-Organic Frameworks, 2015 - Springer
Although the transition d-or 4f-block elements are the most used metals for the construction
of metal–organic frameworks (MOFs), actinide cations were also involved in the elaboration …

A hydrolytically stable uranyl organic framework for highly sensitive and selective detection of Fe 3+ in aqueous media

W Liu, J **e, L Zhang, MA Silver, S Wang - Dalton Transactions, 2018 - pubs.rsc.org
We present a depleted uranium-based metal organic framework, UO2 (C8H3O6N)· DMF,
that exhibits highly sensitive and selective detection towards Fe3+ ions in aqueous media …

An anionic uranium-based metal–organic framework with ultralarge nanocages for selective dye adsorption

F Hu, Z Di, P Lin, P Huang, M Wu, F Jiang… - Crystal Growth & …, 2018 - ACS Publications
We herein present a rarely seen (3, 4)-connected non-interpenetrated anionic uranium-
organic framework with tbo topology (FJI–H-U1), which is constructed from two kinds of …

Recent progress in actinide borate chemistry

S Wang, EV Alekseev, W Depmeier… - Chemical …, 2011 - pubs.rsc.org
The use of molten boric acid as a reactive flux for synthesizing actinide borates has been
developed in the past two years providing access to a remarkable array of exotic materials …