Surface chemistry of porphyrins and phthalocyanines

JM Gottfried - Surface Science Reports, 2015 - Elsevier
This review covers the surface chemistry of porphyrins, phthalocyanines, their metal
complexes, and related compounds, with particular focus on chemical reactions at …

Porphyrins at interfaces

W Auwärter, D Écija, F Klappenberger, JV Barth - Nature chemistry, 2015 - nature.com
Porphyrins and other tetrapyrrole macrocycles possess an impressive variety of functional
properties that have been exploited in natural and artificial systems. Different metal centres …

Coordination and metalation bifunctionality of Cu with 5, 10, 15, 20-tetra (4-pyridyl) porphyrin: toward a mixed-valence two-dimensional coordination network

Y Li, J **ao, TE Shubina, M Chen, Z Shi… - Journal of the …, 2012 - ACS Publications
We investigated the coordination self-assembly and metalation reaction of Cu with 5, 10, 15,
20-tetra (4-pyridyl) porphyrin (2HTPyP) on a Au (111) surface by means of scanning …

Surface-Mediated in Situ Metalation of Porphyrins at the Solid–Vacuum Interface

H Marbach - Accounts of chemical research, 2015 - ACS Publications
Conspectus The investigation of porphyrin derivatives at the solid–vacuum interface has
become a vivid research field with the prospect to tailor functional molecular architectures …

In vacuo interfacial tetrapyrrole metallation

K Diller, AC Papageorgiou, F Klappenberger… - Chemical Society …, 2016 - pubs.rsc.org
The metallation of tetrapyrroles at well-defined surfaces under ultra-high vacuum conditions
represents an unconventional synthesis approach to achieve tetrapyrrole-based metal …

Surface-confined 2D polymerization of a brominated copper-tetraphenylporphyrin on Au (111)

L Smykalla, P Shukrynau, M Korb, H Lang… - Nanoscale, 2015 - pubs.rsc.org
A coupling-limited approach for the Ullmann reaction-like on-surface synthesis of a two-
dimensional covalent organic network starting from a halogenated metallo-porphyrin is …

Temperature-dependent chemical and structural transformations from 2H-tetraphenylporphyrin to copper (II)-tetraphenylporphyrin on Cu (111)

J **ao, S Ditze, M Chen, F Buchner… - The Journal of …, 2012 - ACS Publications
Temperature-dependent chemical and structural changes of a submonolayer of 2H-
tetraphenylporphyrin (2HTPP) on Cu (111) were studied with photoelectron spectroscopy …

Coverage‐and Temperature‐Dependent Metalation and Dehydrogenation of Tetraphenylporphyrin on Cu (111)

M Röckert, M Franke, Q Tariq, S Ditze… - … A European Journal, 2014 - Wiley Online Library
Using temperature‐programmed desorption, supported by X‐ray photoelectron
spectroscopy and scanning tunneling microscopy, a comprehensive overview of the main …

Investigating the molecule-substrate interaction of prototypic tetrapyrrole compounds: Adsorption and self-metalation of porphine on Cu (111)

K Diller, F Klappenberger, F Allegretti… - The Journal of …, 2013 - pubs.aip.org
We report on the adsorption and self-metalation of a prototypic tetrapyrrole compound, the
free-base porphine (2H-P), on the Cu (111) surface. Our multitechnique study combines …

Studying the dynamic behaviour of porphyrins as prototype functional molecules by scanning tunnelling microscopy close to room temperature

H Marbach, HP Steinrück - Chemical Communications, 2014 - pubs.rsc.org
Scanning tunnelling microscopy (STM) enables us to directly observe the dynamic
behaviour of organic molecules on surfaces. While imaging atoms and molecules using …