Tuning the coordination environment of carbon‐based single‐atom catalysts via do** with multiple heteroatoms and their applications in electrocatalysis

Z Qi, Y Zhou, R Guan, Y Fu, JB Baek - Advanced Materials, 2023 - Wiley Online Library
Carbon‐based single‐atom catalysts (SACs) are considered to be a perfect platform for
studying the structure–activity relationship of different reactions due to the adjustability of …

Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Recent advances in the use of nitrogen-doped carbon materials for the design of noble metal catalysts

JL Fiorio, MAS Garcia, ML Gothe, D Galvan… - Coordination Chemistry …, 2023 - Elsevier
Noble metals nanoparticles (NPs) and single atoms (SAs) supported on nitrogen-doped
carbon (NC) materials display remarkable activity and selectivity in a wide variety of …

Microenvironment modulation of single-atom catalysts and their roles in electrochemical energy conversion

X Li, L Liu, X Ren, J Gao, Y Huang, B Liu - Science Advances, 2020 - science.org
Single-atom catalysts (SACs) have become the most attractive frontier research field in
heterogeneous catalysis. Since the atomically dispersed metal atoms are commonly …

Transforming energy with single-atom catalysts

S Ding, MJ Hülsey, J Pérez-Ramírez, N Yan - Joule, 2019 - cell.com
Almost a quarter of the energy consumed globally is directly or indirectly related to the use of
a catalytic process. Conventional nanoparticle-based catalysts recently witnessed the dawn …

Performance descriptors of nanostructured metal catalysts for acetylene hydrochlorination

SK Kaiser, E Fako, I Surin, F Krumeich… - Nature …, 2022 - nature.com
Controlling the precise atomic architecture of supported metals is central to optimizing their
catalytic performance, as recently exemplified for nanostructured platinum and ruthenium …

Nanostructuring unlocks high performance of platinum single-atom catalysts for stable vinyl chloride production

SK Kaiser, E Fako, G Manzocchi, F Krumeich… - Nature …, 2020 - nature.com
The worldwide replacement of the toxic mercuric chloride catalyst in vinyl chloride
manufacture via acetylene hydrochlorination is slowed by the limited durability of alternative …

Advances in single-atom-catalyzed acetylene hydrochlorination

Z Chen, S Wang, J Zhao, R Lin - ACS Catalysis, 2024 - ACS Publications
The growing demand for polyvinyl chloride (PVC) calls for a cleaner technology for its
production. Nonetheless, acetylene hydrochlorination, an industrially relevant technology for …

Asymmetric Ru-In atomic pairs promote highly active and stable acetylene hydrochlorination

Y Fan, H Xu, G Gao, M Wang, W Huang, L Ma… - Nature …, 2024 - nature.com
Ru single-atom catalysts have great potential to replace toxic mercuric chloride in acetylene
hydrochlorination. However, long-term catalytic stability remains a grand challenge due to …

Isolated Iridium Sites on Potassium‐Doped Carbon‐nitride wrapped Tellurium Nanostructures for Enhanced Glycerol Photooxidation

P Kumar, A Askar, J Wang, S Roy… - Advanced Functional …, 2024 - Wiley Online Library
Many industrial processes such transesterification of fatty acid for biodiesel production, soap
manufacturing and biosynthesis of ethanol generate glycerol as a major by‐product that can …