Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry

L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Imide-and amide-functionalized polymer semiconductors

X Guo, A Facchetti, TJ Marks - Chemical reviews, 2014 - ACS Publications
Organic molecular and polymeric semiconductors are attractive for fabrication of cost-
effective, large-area, and mechanically flexible electronic devices via solution-based high …

Donor–acceptor conjugated polymers based on multifused ladder-type arenes for organic solar cells

JS Wu, SW Cheng, YJ Cheng, CS Hsu - Chemical Society Reviews, 2015 - pubs.rsc.org
Harvesting solar energy from sunlight to generate electricity is considered as one of the most
important technologies to address the future sustainability of humans. Polymer solar cells …

Direct (hetero) arylation polymerization: trends and perspectives

T Bura, JT Blaskovits, M Leclerc - Journal of the American …, 2016 - ACS Publications
Conjugated polymers have attracted much attention in recent years, as they can combine
the best features of metals or inorganic semiconducting materials (excellent electrical and …

Direct arylation polymerization: A guide to optimal conditions for effective conjugated polymers

NS Gobalasingham, BC Thompson - Progress in Polymer Science, 2018 - Elsevier
The rapid increase in the breadth and scope of transformations that involve metal-promoted
activation of Csingle bondH bonds is fundamentally changing the field of synthetic …

Optimization of direct arylation polymerization (DArP) through the identification and control of defects in polymer structure

AE Rudenko, BC Thompson - Journal of Polymer Science Part …, 2015 - Wiley Online Library
As a newly emerged protocol for the synthesis of conjugated polymers, direct arylation
polymerization (DArP) is an environmentally friendly and cost‐effective alternative to …

Improving the efficiency and sustainability of catalysts for direct arylation polymerization (DArP)

L Ye, BC Thompson - Journal of Polymer Science, 2022 - Wiley Online Library
In the past decade, direct arylation polymerization (DArP) has rapidly developed as a
sustainable synthetic protocol for cost‐effective, atom‐economical preparation of conjugated …

Thiophene-embedded conjugated microporous polymers for photocatalysis

WK An, SJ Zheng, YN Du, SY Ding, ZJ Li… - Catalysis Science & …, 2020 - pubs.rsc.org
Various photoactive building blocks can be incorporated into porous organic polymers
(POPs). The intrinsic properties, such as various synthetic methods, outstanding inherent …

Electroactive and Photoactive Poly[Isoindigo-alt-EDOT] Synthesized Using Direct (Hetero)Arylation Polymerization in Batch and in Continuous Flow

F Grenier, BR Aïch, YY Lai, M Guérette… - Chemistry of …, 2015 - ACS Publications
In this work, a combined approach was used to obtain a low-cost material for organic
electronics by focusing on inexpensive monomers, short synthetic pathway, high-yielding …