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Collective nanoparticle dynamics associated with bridging network formation in model polymer nanocomposites
The addition of nanoparticles (NPs) to polymers is a powerful method to improve the
mechanical and other properties of macromolecular materials. Such hybrid polymer–particle …
mechanical and other properties of macromolecular materials. Such hybrid polymer–particle …
How tuning interfaces impacts the dynamics and structure of polymer nanocomposites simultaneously
Fundamental understanding of the macroscopic properties of polymer nanocomposites
(PNCs) remains difficult due to the complex interplay of microscopic dynamics and structure …
(PNCs) remains difficult due to the complex interplay of microscopic dynamics and structure …
Mechanism of mechanical reinforcement for weakly attractive nanocomposites in glassy and rubbery states
W Cui, W You, W Yu - Macromolecules, 2021 - ACS Publications
Polymer nanocomposites (PNCs) have been widely investigated due to their significant
performance in mechanical reinforcement, but the mechanism of mechanical reinforcement …
performance in mechanical reinforcement, but the mechanism of mechanical reinforcement …
Mechanical reinforcement by bridging chains in polymer nanocomposites
W Cui, J Liu, W You, W Yu - Polymer, 2024 - Elsevier
The adsorption-induced bridging of polymer chains between adjacent nanoparticles was
studied in poly (vinyl acetate)/silica nanocomposites with different polymer molecular …
studied in poly (vinyl acetate)/silica nanocomposites with different polymer molecular …
Structural and dynamical roles of bound polymer chains in rubber reinforcement
The addition of nanofillers to rubber matrices is a powerful route to improve the mechanical
properties. Here, we focus on a molecular understanding of basic mechanisms that are …
properties. Here, we focus on a molecular understanding of basic mechanisms that are …
Long-term aging in miscible polymer nanocomposites
We find that the initial, solvent-cast state of nanoparticles (NPs) in a polymer matrix
temporally evolves during thermal annealing such that, at steady state, NPs maximize their …
temporally evolves during thermal annealing such that, at steady state, NPs maximize their …
Rationalizing the interfacial layer in polymer nanocomposites: Correlation between enthalpy and dielectric relaxation
R **ao, G Wu, Y Lin - Polymer, 2023 - Elsevier
The accurate and convenient characterization of the interfacial layer is a crucial prerequisite
for understanding the relationship between structure and macroscopic properties in polymer …
for understanding the relationship between structure and macroscopic properties in polymer …
Liquid state theory of the structure of model polymerized ionic liquids
We employ polymer integral equation theory to study a simplified model of semiflexible
polymerized ionic liquids (PolyILs) that interact via hard core repulsions and short range …
polymerized ionic liquids (PolyILs) that interact via hard core repulsions and short range …
Microscopic origins of the nonlinear behavior of particle-filled rubber probed with dynamic strain XPCS
D Presto, S Narayanan, S Moctezuma… - … Applied Materials & …, 2023 - ACS Publications
The underlying microscopic response of filler networks in reinforced rubber to dynamic strain
is not well understood due to the experimental difficulty of directly measuring filler network …
is not well understood due to the experimental difficulty of directly measuring filler network …
Improving gas selectivity in membranes using polymer-grafted silica nanoparticles
Herein, we demonstrate that tuning of structural parameters and material chemistry enables
control of the permeability and selectivity of gases (CO2, He, and CH4) in membranes based …
control of the permeability and selectivity of gases (CO2, He, and CH4) in membranes based …