Incorporating Catalytic Units into Nanomaterials: Rational Design of Multipurpose Catalysts for CO2 Valorization

LQ Qiu, HR Li, LN He - Accounts of chemical research, 2023 - ACS Publications
Conspectus CO2 conversion to valuable chemicals is effective at reducing CO2 emissions.
We previously proposed valorization strategies and developed efficient catalysts to address …

Advancements and challenges in reductive conversion of carbon dioxide via thermo-/photocatalysis

LQ Qiu, X Yao, YK Zhang, HR Li… - The Journal of Organic …, 2022 - ACS Publications
Carbon dioxide (CO2) is the major greenhouse gas and also an abundant and renewable
carbon resource. Therefore, its chemical conversion and utilization are of great attraction for …

Integrating Dual-Metal Sites into Covalent Organic Frameworks for Enhanced Photocatalytic CO2 Reduction

J Wang, W Zhu, F Meng, G Bai, Q Zhang, X Lan - ACS Catalysis, 2023 - ACS Publications
Photocatalytic CO2 reduction holds great promise for synchronously addressing carbon
neutrality and producing fuels, although enhancing the photocatalyst activity and tuning the …

Efficient Photoreduction of Diluted CO2 to Tunable Syngas by Ni−Co Dual Sites through d‐band Center Manipulation

G Qian, W Lyu, X Zhao, J Zhou, R Fang… - Angewandte Chemie …, 2022 - Wiley Online Library
Photocatalytic conversion of CO2 into syngas is a promising way to address the energy and
environmental challenges. Here we report the integration of Ni− Co dual sites on Ni doped …

Rational design of MoS2@ COF hybrid composites promoting CC coupling for photocatalytic CO2 reduction to ethane

X Yang, X Lan, Y Zhang, H Li, G Bai - Applied Catalysis B: Environmental, 2023 - Elsevier
Photocatalytic CO 2 reduction into high-value C 2+ products such as ethane is quite exciting
but challenging due to multielectron steps involved and sluggish CC coupling kinetics …

Highly Selective CO2 Electroreduction to C2H4 Using a Dual‐Sites Cu(II) Porphyrin Framework Coupled with Cu2O Nanoparticles via a Synergetic‐Tandem …

Q He, H Li, Z Hu, L Lei, D Wang… - Angewandte Chemie …, 2024 - Wiley Online Library
Low* CO coverage on the active sites is a major hurdle in the tandem electrocatalysis,
resulting in unsatisfied C2H4 production efficiencies. In this work, we developed a …

Pyrazine‐Functionalized Donor–Acceptor Covalent Organic Frameworks for Enhanced Photocatalytic H2 Evolution with High Proton Transport

FD Wang, LJ Yang, XX Wang, Y Rong, LB Yang… - Small, 2023 - Wiley Online Library
The well‐defined 2D or 3D structure of covalent organic frameworks (COFs) makes it have
great potential in photoelectric conversion and ions conduction fields. Herein, a new donor …

Spin Manipulation in a Metal–Organic Layer through Mechanical Exfoliation for Highly Selective CO2 Photoreduction

D Wu, HQ Yin, Z Wang, M Zhou, C Yu, J Wu… - Angewandte …, 2023 - Wiley Online Library
Spin manipulation of transition‐metal catalysts has great potential in mimicking enzyme
electronic structures to improve activity and/or selectivity. However, it remains a great …

Visible-light-driven production of solar fuels catalyzed by nanosized porphyrin-based metal–organic frameworks and covalent–organic frameworks: A Review

P Asselin, PD Harvey - ACS Applied Nano Materials, 2022 - ACS Publications
Porphyrin-based materials are excellent chromophores because they strongly absorb visible
light and their relatively low-energy lowest unoccupied molecular orbitals …

Fabrication and properties of Sn (IV) porphyrin-linked porous organic polymer for environmental applications

CJ Lee, NK Shee, HJ Kim - RSC advances, 2023 - pubs.rsc.org
A robust porous organic polymer cross-linked by Sn (IV) porphyrin (SnPOP) was fabricated
by reacting trans-dihydroxo-[5, 15, 10, 20-tetrakis (phenyl) porphyrinato] tin (IV)(SnP) with …