Understanding and Design of Cathode–Electrolyte Interphase in High‐Voltage Lithium–Metal Batteries

W Li, Z He, Y Jie, F Huang, Y Chen… - Advanced Functional …, 2024 - Wiley Online Library
The development of lithium–metal batteries (LMBs) has emerged as a mainstream approach
for achieving high‐energy‐density energy storage devices. The stability of electrochemical …

Understanding the transport mechanism of lithium ions in solid-electrolyte interphase in lithium metal batteries with liquid electrolytes

SY Sun, XQ Zhang, YN Wang, JL Li, Z Zheng… - Materials Today, 2024 - Elsevier
Lithium (Li) metal battery is regarded as a high-energy-density battery system beyond Li-ion
battery. However, the cycle life of Li metal batteries with liquid electrolytes is severely …

Factors Influencing Gas Evolution from High‐Nickel Layered Oxide Cathodes in Lithium‐Based Batteries

R Sim, A Manthiram - Advanced Energy Materials, 2024 - Wiley Online Library
Gas evolution from high‐nickel layered oxide cathodes (> 90% Ni) remains a major issue for
their practical application. Gaseous species, such as CO2, O2, and CO, that are evolved at …

Enabling Stable Operation of Lithium‐Ion Batteries under Fast‐Operating Conditions by Tuning the Electrolyte Chemistry

Z Cui, C Liu, A Manthiram - Advanced Materials, 2024 - Wiley Online Library
Inferior fast‐charging and low‐temperature performances remain a hurdle for lithium‐ion
batteries. Overcoming this hurdle is extremely challenging primarily due to the low …

Five Volts Lithium Batteries with Advanced Carbonate‐Based Electrolytes: A Rational Design via a Trio‐Functional Addon Materials

F Zhang, P Zhang, W Zhang, PR Gonzalez… - Advanced …, 2024 - Wiley Online Library
Lithium metal batteries paired with high‐voltage LiNi0. 5Mn1. 5O4 (LNMO) cathodes are a
promising energy storage source for achieving enhanced high energy density. Forming …

Sodium–Sulfur Cells with a Sulfurized Polyacrylonitrile Cathode and a Localized High Concentration Electrolyte with Toluene as a Nonfluorinated Diluent

MH Pai, T Lai, A Manthiram - Advanced Functional Materials, 2024 - Wiley Online Library
Room‐temperature sodium–sulfur (Na–S) batteries are recognized as promising candidates
for next‐generation scalable energy storage systems due to their high energy density and …

Additive engineering strategies for improved interfacial stability in lithium metal batteries

K Ryu, K Lee, J Lim, MJ Lee, KH Kim, UH Lee… - Energy & …, 2024 - pubs.rsc.org
Electrolyte engineering is crucial for advancing lithium (Li) metal batteries (LMBs). Currently,
unstable electrode–electrolyte interfaces limit the stable cycling of LMBs. Here, we introduce …

Perspective on Recent Advances of Functional Electrolytes for Lithium Metal Batteries

L Bai, B Chen, D Zhang, Y Xu, S Zhang, Y He… - Energy & …, 2024 - ACS Publications
Lithium metal batteries (LMBs) have attracted extensive research interest because of their
unparalleled electrochemical performances. Electrolytes, a critical component of batteries …

Enabling High Stability of Co-Free LiNiO2 Cathode via a Sulfide-Enriched Cathode Electrolyte Interface

Z Bai, Z Ying, F Zhang, W Wang, Z Huang… - ACS Energy …, 2024 - ACS Publications
Cobalt-free lithium nickel oxide (LNO) has garnered significant interest as the end member
of high-nickel layered oxide cathodes for next-generation batteries. However, its practical …

Operando chemo-mechanical evolution in LiNi0.8Co0.1Mn0.1O2 cathodes

Y Zhang, S Hao, F Pei, X **ao, C Lu, X Lin… - National Science …, 2024 - academic.oup.com
ABSTRACT Ni-rich LiNi x Co y Mn z O2 (NCM xyz, x+ y+ z= 1, x≥ 0.8) layered oxide
materials are considered the main cathode materials for high-energy-density Li-ion …