The GW Compendium: A Practical Guide to Theoretical Photoemission Spectroscopy

D Golze, M Dvorak, P Rinke - Frontiers in chemistry, 2019‏ - frontiersin.org
The GW approximation in electronic structure theory has become a widespread tool for
predicting electronic excitations in chemical compounds and materials. In the realm of …

Combining wave function methods with density functional theory for excited states

S Ghosh, P Verma, CJ Cramer, L Gagliardi… - Chemical …, 2018‏ - ACS Publications
We review state-of-the-art electronic structure methods based both on wave function theory
(WFT) and density functional theory (DFT). Strengths and limitations of both the wave …

The Bethe–Salpeter equation formalism: From physics to chemistry

X Blase, I Duchemin, D Jacquemin… - The Journal of Physical …, 2020‏ - ACS Publications
The Bethe–Salpeter equation (BSE) formalism is steadily asserting itself as a new efficient
and accurate tool in the ensemble of computational methods available to chemists in order …

Fully self-consistent finite-temperature in Gaussian Bloch orbitals for solids

CN Yeh, S Iskakov, D Zgid, E Gull - Physical Review B, 2022‏ - APS
We present algorithmic and implementation details for the fully self-consistent finite-
temperature GW method in Gaussian Bloch orbitals for solids. Our implementation is based …

Cubic-Scaling All-Electron GW Calculations with a Separable Density-Fitting Space–Time Approach

I Duchemin, X Blase - Journal of Chemical Theory and …, 2021‏ - ACS Publications
We present an implementation of the GW space–time approach that allows cubic-scaling all-
electron calculations with standard Gaussian basis sets without exploiting any localization or …

The GW miracle in many-body perturbation theory for the ionization potential of molecules

F Bruneval, N Dattani, MJ van Setten - Frontiers in chemistry, 2021‏ - frontiersin.org
We use the GW100 benchmark set to systematically judge the quality of several perturbation
theories against high-level quantum chemistry methods. First of all, we revisit the reference …

Toward GW Calculations on Thousands of Atoms

J Wilhelm, D Golze, L Talirz, J Hutter… - The journal of physical …, 2018‏ - ACS Publications
The GW approximation of many-body perturbation theory is an accurate method for
computing electron addition and removal energies of molecules and solids. In a canonical …

Sparse sampling approach to efficient ab initio calculations at finite temperature

J Li, M Wallerberger, N Chikano, CN Yeh, E Gull… - Physical Review B, 2020‏ - APS
Efficient ab initio calculations of correlated materials at finite temperatures require compact
representations of the Green's functions both in imaginary time and in Matsubara frequency …

Core-Level Binding Energies from GW: An Efficient Full-Frequency Approach within a Localized Basis

D Golze, J Wilhelm, MJ Van Setten… - Journal of chemical …, 2018‏ - ACS Publications
The GW method is routinely used to predict charged valence excitations in molecules and
solids. However, the numerical techniques employed in the most efficient GW algorithms …

Low-order scaling quasiparticle self-consistent GW for molecules

A Förster, L Visscher - Frontiers in Chemistry, 2021‏ - frontiersin.org
Low-order scaling GW implementations for molecules are usually restricted to
approximations with diagonal self-energy. Here, we present an all-electron implementation …