Abstract The stereospecific 1, 2‐migration of boronate complexes is one of the most
representative reactions in boron chemistry. This process has been used extensively to …

The Zweifel olefination is a powerful method for the stereoselective synthesis of alkenes.
The reaction proceeds in the absence of a transition-metal catalyst, instead taking place by …

The formation of highly enantioenriched boronic esters through both stoichiometric and
catalytic methods has received much attention over the past decade. Accordingly, the …

A strategy that facilitates the construction of a wide variety of trisubstituted stereocenters
through a catalytically accessed common chiral intermediate could prove highly enabling for …

Abstract A modular, site‐selective 1, 2‐dicarbofunctionalization of vinyl boronates with
organic halides through dual catalysis is described. This reaction proceeds under mild …

Alkylboron compounds are an important family of target molecules, serving as useful
intermediates, as well as end points, in fields such as pharmaceutical science and organic …

Alkyl boronic acids and esters play an important role in the synthesis of C (sp3)-rich
medicines, agrochemicals, and material chemistry. This work describes a new type of …

Polyketide natural products often contain common repeat motifs, for example, propionate,
acetate and deoxypropionate, and so can be synthesized by iterative processes. We report …

Abstract A catalytic 1, 1‐difunctionalization of unactivated olefins en route to sp3 bis‐
organometallic B, B (Si)‐reagents is described. The protocol is characterized by exceptional …

We report an efficient and highly enantioselective hydroboration of aliphatic 1, 1-
disubstituted alkenes with pinacolborane using a phosphine-Cu catalyst. The method allows …