Ligand Design in Atomically Precise Copper Nanoclusters and Their Application in Electrocatalytic Reactions

Y Liu, J Yu, Y Lun, Y Wang, Y Wang… - Advanced Functional …, 2023 - Wiley Online Library
Metal nanoclusters (MNCs) are compositionally well‐defined and also structurally precise
materials with unique molecule‐like properties and discrete electronic energy levels …

Atomically precise metal nanoclusters as catalysts for electrocatalytic CO 2 reduction

T Kawawaki, T Okada, D Hirayama, Y Negishi - Green Chemistry, 2024 - pubs.rsc.org
Electrochemical carbon dioxide (CO2) reduction can be used to convert CO2 into various
compounds at room temperature and ambient pressure using electricity generated from …

Multilevel-Regulated Metal–Organic Framework Platform Integrating Pore Space Partition and Open-Metal Sites for Enhanced CO2 Photoreduction to CO with Nearly …

HL Zheng, JQ Zhao, YY Sun, AA Zhang… - Journal of the …, 2023 - ACS Publications
Rational design and regulation of atomically precise photocatalysts are essential for
constructing efficient photocatalytic systems tunable at both the atomic and molecular levels …

Copper Do** Boosts Electrocatalytic CO2 Reduction of Atomically Precise Gold Nanoclusters

G Deng, H Yun, MS Bootharaju, F Sun… - Journal of the …, 2023 - ACS Publications
Unraveling the atomistic synergistic effects of nanoalloys on the electrocatalytic CO2
reduction reaction (eCO2RR), especially in the presence of copper, is of paramount …

In Situ Pyrolysis of ZIF-67 to Construct Co2N0.67@ZIF-67 for Photocatalytic CO2 Cycloaddition Reaction

L Jiang, D Wu, Z Huang, F Chen, K Chen… - Inorganic …, 2024 - ACS Publications
The development of heterogeneous catalysts with abundant active sites is pivotal for
enhancing the efficiency of photothermal CO2 conversion. Herein, we report the construction …

Symmetry Breaking Enhancing the Activity of Electrocatalytic CO2 Reduction on an Icosahedron‐Kernel Cluster by Cu Atoms Regulation

Y Tan, G Sun, T Jiang, D Liu, Q Li… - Angewandte Chemie …, 2024 - Wiley Online Library
Recently, CO2 hydrogenation had a new breakthrough resulting from the design of catalysts
to effectively activate linear CO2 with symmetry‐breaking sites. However, understanding the …

Recent progress in atomically precise metal nanoclusters for photocatalytic application

Y Du, C Li, Y Dai, H Yin, M Zhu - Nanoscale Horizons, 2024 - pubs.rsc.org
Photocatalysis is a widely recognized green and sustainable technology that can harness
inexhaustible solar energy to carry out chemical reactions, offering the opportunity to …

Strategies for Enhancing the Photocatalytic and Electrocatalytic Efficiency of Covalent Triazine Frameworks for CO2 Reduction

G Liu, S Liu, C Lai, L Qin, M Zhang, Y Li, M Xu, D Ma… - Small, 2024 - Wiley Online Library
Converting carbon dioxide (CO2) into fuel and high‐value‐added chemicals is considered a
green and effective way to solve global energy and environmental problems. Covalent …

Nanocluster Surface Microenvironment Modulates Electrocatalytic CO2 Reduction

S Yoo, S Yoo, G Deng, F Sun, K Lee, H Jang… - Advanced …, 2024 - Wiley Online Library
The catalytic activity and product selectivity of the electrochemical CO2 reduction reaction
(eCO2RR) depend strongly on the local microenvironment of mass diffusion at the …

Size effects of atomically precise gold nanoclusters in catalysis

S Li, X Du, Z Liu, Y Li, Y Shao, R ** - Precision Chemistry, 2023 - ACS Publications
The emergence of ligand-protected, atomically precise gold nanoclusters (NCs) in recent
years has attracted broad interest in catalysis due to their well-defined atomic structures and …