Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …
polaritons, are formed due to quantum light–matter interactions. With the experimental …
The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Chemistry under vibrational strong coupling
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …
Quantum dynamical effects of vibrational strong coupling in chemical reactivity
Recent experiments suggest that ground state chemical reactivity can be modified when
placing molecular systems inside infrared cavities where molecular vibrations are strongly …
placing molecular systems inside infrared cavities where molecular vibrations are strongly …
Control, modulation, and analytical descriptions of vibrational strong coupling
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
Molecular chemistry in cavity strong coupling
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …
matter interactions and so-called polaritonic states with intriguing properties, halfway …
Molecular polaritonics: Chemical dynamics under strong light–matter coupling
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …
intense experimental and theoretical studies. Here we review the present status of this field …
Cavity frequency-dependent theory for vibrational polariton chemistry
Recent experiments demonstrate the control of chemical reactivities by coupling molecules
inside an optical microcavity. In contrast, transition state theory predicts no change of the …
inside an optical microcavity. In contrast, transition state theory predicts no change of the …
Vibration-cavity polariton chemistry and dynamics
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …
molecular electronic or vibrational transitions. When the coupling is strong enough, new …
Shining light on the microscopic resonant mechanism responsible for cavity-mediated chemical reactivity
Strong light–matter interaction in cavity environments is emerging as a promising approach
to control chemical reactions in a non-intrusive and efficient manner. The underlying …
to control chemical reactions in a non-intrusive and efficient manner. The underlying …