Self-assembled monolayers for interfacial engineering in solution-processed thin-film electronic devices: design, fabrication, and applications

M Li, M Liu, F Qi, FR Lin, AKY Jen - Chemical Reviews, 2024 - ACS Publications
Interfacial engineering has long been a vital means of improving thin-film device
performance, especially for organic electronics, perovskites, and hybrid devices. It greatly …

Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles

G Kaur, RL Thimes, JP Camden… - Chemical …, 2022 - pubs.rsc.org
The discovery of N-heterocyclic carbenes (NHCs) revolutionized organometallic chemistry
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …

On-surface synthesis of ballbot-type N-heterocyclic carbene polymers

J Ren, M Koy, H Osthues, BS Lammers, C Gutheil… - Nature Chemistry, 2023 - nature.com
N-Heterocyclic carbenes (NHCs) are established ligands for metal complexes and surfaces.
Here we go beyond monomeric NHCs and report on the synthesis of NHC polymers on gold …

Deposition condition impacts charge tunneling and thermoelectric properties of N-heterocyclic carbene monolayers

H Kang, J Jang, GD Kong, S Jung, T Ohto… - Journal of Materials …, 2023 - pubs.rsc.org
N-heterocyclic carbene (NHC) is an emerging anchor moiety for surface engineering and
various applications. While various deposition conditions have been reported, how these …

Asymmetric Twisting of C-Centered Octahedral Gold(I) Clusters by Chiral N-Heterocyclic Carbene Ligation

XL Pei, P Zhao, H Ube, Z Lei, K Nagata… - Journal of the …, 2022 - ACS Publications
Asymmetric induction of metal clusters by ligation of chiral ligands is intriguing in terms of the
mechanism of chirality transfer and the stability of the resulting chiral structure. Here we …

Progress in optical properties of chiral metal clusters: circular dichroism and circularly polarized luminescence

BW Zhou, S Zhang, L Zhao - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
The design of metal cluster-based materials exhibiting exceptional circular dichroism (CD)
and circularly polarized luminescence (CPL) performance has garnered significant attention …

A Chemist's View on Electronic and Steric Effects of Surface Ligands on Plasmonic Metal Nanostructures

Y Kim, S Ji, JM Nam - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Plasmonic metal nanostructures have been extensively developed over the
past few decades because of their ability to confine light within the surfaces and manipulate …

What It Takes for Imidazolium Cations to Promote Electrochemical Reduction of CO2

S Neyrizi, J Kiewiet, MA Hempenius, G Mul - ACS Energy Letters, 2022 - ACS Publications
Imidazolium cations enhance the performance of several electrodes in converting CO2 to
CO in non-aqueous media. In this publication, we elucidate the origin of the function of …

Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation

MA Pellitero, IM Jensen, NL Dominique… - … Applied Materials & …, 2023 - ACS Publications
N-Heterocyclic carbenes (NHCs) are promising monolayer-forming ligands that can
overcome limitations of thiol-based monolayers in terms of stability, surface functionality, and …

Controlled growth of ordered monolayers of N-heterocyclic carbenes on silicon

M Franz, S Chandola, M Koy, R Zielinski… - Nature Chemistry, 2021 - nature.com
N-Heterocyclic carbenes (NHCs) are promising modifiers and anchors for surface
functionalization and offer some advantages over thiol-based systems. Because of their …