Copper-catalyzed decarboxylative reactions of propargylic cyclic carbonates/carbamates
enable the efficient construction of widely available skeletons such as allenes, ethynyl …

Conspectus Biologically active compounds and pharmaceutically relevant intermediates
often feature sterically congested stereogenic centers, in particular, carbon stereocenters …

Two general protocols for the regioselective electrochemically enabled sulfonylation
cyclization of N-alkenylacrylamides with sodium sulfinates or sulfonyl hydrazides were …

Catalytic asymmetric transformations by dearomatization have developed into a widely
applicable synthetic strategy, but heavily relied on the use of arenes bearing a heteroatom …

Catalytic asymmetric propargylic substitution reactions have received phenomenal progress
and applications, but no study focuses on CO2 gas capture and fixation in this area. The …

Copper-catalyzed enantioselective propargylic substitution has become an increasingly
reliable strategy to construct stereogenic centers over the past two decades. Currently …

Despite binuclear Cu active sites present in some biological and heterogeneous catalysts,
the development of chiral binuclear copper catalysts is still in its infancy and remains a …

Transition-metal-catalyzed asymmetric allylic alkylation is one of the most powerful and well-
known strategies for the construction of C–C bonds; nevertheless, propargylation is elusive …

Here, we describe a strategy for the copper-catalyzed asymmetric heteroarylation of yne-
thiophene carbonates with indoles via remote substitution. The key to the success of this …

A base-free, copper-catalyzed enantioselective O, S-rearrangement of propargylic xanthates
has been developed to enable efficient synthesis of chiral propargylic sulfur compounds in …