[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …

Role of electron spin dynamics and coupling network in designing dynamic nuclear polarization

A Equbal, SK Jain, Y Li, K Tagami, X Wang… - Progress in Nuclear …, 2021 - Elsevier
Dynamic nuclear polarization (DNP) has emerged as a powerful sensitivity booster of
nuclear magnetic resonance (NMR) spectroscopy for the characterization of biological …

Theory for cross effect dynamic nuclear polarization under magic-angle spinning in solid state nuclear magnetic resonance: The importance of level crossings

KR Thurber, R Tycko - The Journal of chemical physics, 2012 - pubs.aip.org
We present theoretical calculations of dynamic nuclear polarization (DNP) due to the cross
effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin …

Theoretical aspects of magic angle spinning-dynamic nuclear polarization

F Mentink-Vigier, U Akbey, H Oschkinat, S Vega… - Journal of Magnetic …, 2015 - Elsevier
Abstract Magic Angle Spinning (MAS) combined with Dynamic Nuclear Polarization (DNP)
has been proven in recent years to be a very powerful method for increasing solid-state …

Fast and accurate MAS–DNP simulations of large spin ensembles

F Mentink-Vigier, S Vega, G De Paëpe - Physical Chemistry Chemical …, 2017 - pubs.rsc.org
A deeper understanding of parameters affecting Magic Angle Spinning Dynamic Nuclear
Polarization (MAS–DNP), an emerging nuclear magnetic resonance hyperpolarization …

Theoretical aspects of dynamic nuclear polarization in the solid state–spin temperature and thermal mixing

Y Hovav, A Feintuch, S Vega - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
Dynamic nuclear polarization is a method which allows for a dramatic increase of the NMR
signals due to polarization transfer between electrons and their neighboring nuclei, via …

Full-scale ab initio simulation of magic-angle-spinning dynamic nuclear polarization

FA Perras, M Raju, SL Carnahan… - The Journal of …, 2020 - ACS Publications
Theoretical models aimed at describing magic-angle-spinning (MAS) dynamic nuclear
polarization (DNP) NMR have great potential in facilitating the in silico design of DNP …

The electron depolarization during dynamic nuclear polarization: measurements and simulations

Y Hovav, I Kaminker, D Shimon, A Feintuch… - Physical Chemistry …, 2015 - pubs.rsc.org
Dynamic nuclear polarization is typically explained either using microscopic systems, such
as in the solid effect and cross effect mechanisms, or using the macroscopic formalism of …

Off-resonance NOVEL

SK Jain, G Mathies, RG Griffin - The Journal of Chemical Physics, 2017 - pubs.aip.org
Dynamic nuclear polarization (DNP) is theoretically able to enhance the signal in nuclear
magnetic resonance (NMR) experiments by a factor γ e/γ n, where γ's are the gyromagnetic …

A versatile and modular quasi optics-based 200 GHz dual dynamic nuclear polarization and electron paramagnetic resonance instrument

TA Siaw, A Leavesley, A Lund, I Kaminker… - Journal of Magnetic …, 2016 - Elsevier
Solid-state dynamic nuclear polarization (DNP) at higher magnetic fields (> 3 T) and
cryogenic temperatures (∼ 2–90 K) has gained enormous interest and seen major …