Erbium salts as non-toxic catalysts compatible with alternative reaction media

M Oliverio, M Nardi, P Costanzo, ML Di Gioia… - Sustainability, 2018 - mdpi.com
Green catalysts must be non-toxic, easy to manage, able to be recovered and reused, active
under alternative reaction conditions and cheap. Erbium salts meet all the previously listed …

Synthesis, biological evaluation, and molecular modeling of oleuropein and its semisynthetic derivatives as cyclooxygenase inhibitors

A Procopio, S Alcaro, M Nardi, M Oliverio… - Journal of agricultural …, 2009 - ACS Publications
Oleuropein, the main phenolic compound in virgin olive oil, and several of its derivatives
such as oleuropein aglycone, hydroxytyrosol, and their respective acetylated lipophilic forms …

Samarium (III) Triflate in Organic Synthesis: a Mild and Efficient Catalyst

AK Dey, S Majhi - ChemistrySelect, 2023 - Wiley Online Library
Lanthanides have shown great potential in the field of magnetic materials,
telecommunications, hard‐disk drives, catalysis, medicine, agriculture, and more. Recently …

Synthesis and antioxidant evaluation of lipophilic oleuropein aglycone derivatives

M Nardi, S Bonacci, L Cariati, P Costanzo, M Oliverio… - Food & function, 2017 - pubs.rsc.org
Oleuropein is the most important phenolic compound present in olive cultivars, but it is
scarcely present in extra virgin olive oil (EVOO) due to its high hydrophilicity and …

Highly efficient and versatile chemoselective addition of amines to epoxides in water catalyzed by erbium (III) triflate

A Procopio, M Gaspari, M Nardi, M Oliverio, O Rosati - Tetrahedron Letters, 2008 - Elsevier
Er (OTf) 3 is proposed as a highly efficient and reusable catalyst for the opening of epoxides
in water with aliphatic as well as aromatic amines leading to the synthesis of β-amino …

Biomimetic synthesis and antioxidant evaluation of 3, 4-DHPEA-EDA [2-(3, 4-hydroxyphenyl) ethyl (3S, 4E)-4-formyl-3-(2-oxoethyl) hex-4-enoate]

M Nardi, S Bonacci, G De Luca, J Maiuolo, M Oliverio… - Food chemistry, 2014 - Elsevier
Phenolic compounds present in extra virgin olive oil have attracted considerable recent
attention. Many of them, show specific anti-inflammatory and anti-tumor activities. In this …

Erbium (III) triflate: A valuable catalyst for the synthesis of aldimines, ketimines, and enaminones

R Dalpozzo, A De Nino, M Nardi, B Russo… - Synthesis, 2006 - thieme-connect.com
Aldimines, ketimines, and enaminones can be obtained under erbium (III) triflate catalysis.
The reaction mechanism is that typical of imine synthesis. The role of the catalyst is …

[PDF][PDF] A Mesoporous ErIII‐MCM‐41 Catalyst for the Cyanosilylation of Aldehydes and Ketones under Solvent‐free Conditions

A Procopio, G Das, M Nardi, M Oliverio… - … & Sustainability Energy …, 2008 - academia.edu
To perform organic reactions without solvents is one of the most important challenges for
organic chemists from both an economic and environmental standpoint because it would …

One‐Pot Synthesis of cis‐Isoquinolonic Acid Derivatives via Three‐Component Reaction of Homophthalic Anhydride with Aldehydes and Amines using Ytterbium(III) …

L Wang, J Liu, H Tian, C Qian… - Advanced Synthesis & …, 2005 - Wiley Online Library
Ytterbium (III) triflate efficiently catalyzes the one‐pot reaction of homophthalic anhydride
with aldehydes and amines at ambient temperature to afford the corresponding cis …

An eco-sustainable erbium (III)-catalyzed method for formation/cleavage of O-tert-butoxy carbonates

A Procopio, G Cravotto, M Oliverio, P Costanzo… - Green chemistry, 2011 - pubs.rsc.org
A new simple and effective method for the formation/cleavage of O-tert-butoxy carbonates of
alcohols and phenols is proposed. Mesoporous silica-supported Er (III)(ErIII-MCM-41) was …