The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Because of the unique properties of the trifluoromethoxy group, molecules bearing this
moiety will find applications in various fields, particularly in the life sciences. However …

A catalytic transfer-hydrogenation utilizing a well-defined Bi (I) complex as catalyst and
ammonia-borane as transfer agent has been developed. This transformation represents a …

Abstract Trifluoromethoxy (OCF3) and difluoromethoxy (OCF2H) groups are fluorinated
structural motifs that exhibit unique physicochemical characteristics. Incorporation of these …

A simple trifluoromethoxylation method enables non‐directed functionalization of C− H
bonds on a range of substrates, providing access to aryl trifluoromethyl ethers. This light …

Aufgrund der einzigartigen Eigenschaften der Trifluormethoxygruppe finden Moleküle, die
diesen Baustein enthalten, in verschiedenen Bereichen Anwendung, besonders in den …

New entries toward the synthesis of OCF 3 -containing molecules - Organic Chemistry
Frontiers (RSC Publishing) DOI:10.1039/C6QO00164E Royal Society of Chemistry View PDF …

Abstract A copper‐CF2H complex generated in situ from copper thiocyanate and TMS
CF2H smoothly converts organothiocyanates into valuable difluoromethyl thioethers. This …

Trifluoromethyl benzoate (TFBz) is developed as a new shelf-stable trifluoromethoxylation
reagent, which can be easily prepared from inexpensive starting materials using KF as the …

Abstract ortho‐Aminophenols are aromatic derivatives featuring vicinal N‐and O‐based
functionalities commonly found in the structures of many high‐value materials. These …