Metal-mediated and metal-catalyzed reactions of isocyanides

VP Boyarskiy, NA Bokach, KV Luzyanin… - Chemical …, 2015 - ACS Publications
1. INTRODUCTION A timely subtitle to this Review focused on conversions of isocyanides at
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …

1, 3-Dipolar cycloaddition of nitrone-type dipoles to uncomplexed and metal-bound substrates bearing the CN triple bond

NA Bokach, ML Kuznetsov, VY Kukushkin - Coordination Chemistry …, 2011 - Elsevier
Metal-free and metal-mediated routes for 1, 3-dipolar cycloaddition of nitrone-type dipoles to
substrates bearing the CN triple bond are compared and the reactions are categorized. In 1 …

Palladium mesoporous nanoparticles Pd NPs@[KIT-6] and Pd NPs@[KIT-6]-PEG-imid as efficient heterogeneous catalysts for H2 production from NaBH4 hydrolysis

H Al-shaikh, J Lasri, JG Knight, ST Al-Goul - Fuel, 2022 - Elsevier
The ordered mesoporous silica supported Pd NPs, denoted as Pd NPs@[KIT-6] 2 and Pd
NPs@[KIT-6]-PEG-imid 6, were synthesized by a deposition precipitation method using the …

Synthesis, X-ray, Hirshfeld combined with DFT, anticancer effects with molecular docking confirmation of (E)-4-cyanobenzaldehyde oxime and (Z)–N-methyl-C-4 …

J Lasri, SM Soliman, EMM Ali, NE Eltayeb… - Journal of Molecular …, 2024 - Elsevier
Abstract (E)-4-cyanobenzaldehyde oxime 1 and (Z)–N-methyl-C-4-substituted phenyl
aldonitrones 2 and 3 were synthesised and fully characterised. With the help of Hirshfeld …

Recent advances in biopolymer supported palladium in organic synthesis

A Kumbhar, R Salunkhe - Current Organic Chemistry, 2015 - ingentaconnect.com
This review mainly discusses the various supporting tactics that have been used for the
immobilization of Pd complexes, and Pd nanoparticles typically on biopolymers, and the …

Oxadiazoline and ketoimine palladium (II) complexes supported on a chitosan membrane and their catalytic activity for the microwave-assisted Suzuki–Miyaura cross …

J Lasri, TCO Mac Leod, AJL Pombeiro - Applied Catalysis A: General, 2011 - Elsevier
The fused bicyclic Δ4-1, 2, 4-oxadiazoline trans-() palladium (II) complex 1 (R= p-ClC6H4),
in refluxing chloroform, undergoes N–O bond cleavage of the oxadiazoline ring to furnish …

Pd nanoparticle-silica nanotubes (Pd@ SNTs) as an efficient catalyst for Suzuki–Miyaura coupling and sp 2 C–H arylation in water

G Park, S Lee, SJ Son, S Shin - Green Chemistry, 2013 - pubs.rsc.org
Silica nanotubes (SNTs) functionalized with Pd-NPs on the inner surface performed as
efficient nano-reactors for C–C coupling in water; the nano-confinement offers minimized …

Oxadiazoline and Ketoimine Palladium (II) Complexes as Highly Efficient Catalysts for Suzuki–Miyaura Cross‐Coupling Reactions in Supercritical Carbon Dioxide

RR Fernandes, J Lasri, MFCG da Silva… - Advanced Synthesis …, 2011 - Wiley Online Library
Abstract The [2+ 3] cycloaddition of nitriles (RCN) with 2, 2‐dimethyl‐3, 4‐dihydro‐2H‐
pyrrole 1‐oxide, in the presence of palladium dichloride (PdCl2) gives the corresponding 2 …

Construction of spiro-1, 2, 4-oxadiazoline-fused matrine-type alkaloids as pesticidal agents

M Lv, Q Ma, S Zhang, H Xu - Bioorganic & Medicinal Chemistry Letters, 2021 - Elsevier
In order to increase the agricultural properties of matrine, a series of novel matrine-type
alkaloids containing spiro-1, 2, 4-oxadiazoline fragment at the C-15 position were prepared …

A palladium (II) Center activates nitrile ligands toward 1, 3-dipolar cycloaddition of nitrones substantially more than the corresponding platinum (II) center

AS Kritchenkov, NA Bokach, GL Starova… - Inorganic …, 2012 - ACS Publications
Palladium (II)-coordinated NCR1 (R1= Et (1), NMe2 (2), Ph (3)) species react smoothly with
acyclic nitrones such as the ketonitrones Ph2C N (O) R4 (R4= p-MeC6H4 (4), p-ClC6H4 …