Theoretical understanding of anisotropy in molecular nanomagnets
LF Chibotaru - Molecular nanomagnets and related phenomena, 2015 - Springer
The study of magnetic anisotropy in metal complexes is at the forefront of current molecular
magnetism research because it represents the key property for potential application of …
magnetism research because it represents the key property for potential application of …
12-MC-4 metallacrowns as versatile tools for SMM research
P Happ, C Plenk, E Rentschler - Coordination Chemistry Reviews, 2015 - Elsevier
The outstanding chemical and structural features of 12-MC-4 metallacrowns allow for
versatile applications in magneto-chemical research. Herein, we present three novel …
versatile applications in magneto-chemical research. Herein, we present three novel …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
Cyanide single-molecule magnets exhibiting solvent dependent reversible “on” and “off” exchange bias behavior
The syntheses, structures, and magnetic properties of four new complex salts,(PPN){[MnIII
(salphen)(MeOH)] 2 [MIII (CN) 6]}· 7MeOH (Mn2M· 7MeOH)(M= Fe, Ru, Os and Co; PPN+ …
(salphen)(MeOH)] 2 [MIII (CN) 6]}· 7MeOH (Mn2M· 7MeOH)(M= Fe, Ru, Os and Co; PPN+ …
A single-molecule magnet based on heptacyanomolybdate with the highest energy barrier for a cyanide compound
K Qian, XC Huang, C Zhou, XZ You… - Journal of the …, 2013 - ACS Publications
Three trinuclear Mn2Mo molecules based on the orbitally degenerate [Mo (CN) 7] 4–anion
were prepared, one of which is the first single-molecule magnet (SMM) based on …
were prepared, one of which is the first single-molecule magnet (SMM) based on …
Measurement of magnetic exchange in asymmetric lanthanide dimetallics: toward a transferable theoretical framework
Magnetic exchange interactions within the asymmetric dimetallic compounds [hqH2][Ln2
(hq) 4 (NO3) 3]· MeOH,(Ln= Er (III) and Yb (III), hqH= 8-hydroxyquinoline) have been directly …
(hq) 4 (NO3) 3]· MeOH,(Ln= Er (III) and Yb (III), hqH= 8-hydroxyquinoline) have been directly …
Modelling spin Hamiltonian parameters of molecular nanomagnets
Molecular nanomagnets encompass a wide range of coordination complexes possessing
several potential applications. A formidable challenge in realizing these potential …
several potential applications. A formidable challenge in realizing these potential …
Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes
AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …
been actively studied for potential applications in the new generation of high-density data …
Recent progress in synchrotron-based frequency-domain Fourier-transform THz-EPR
We describe frequency-domain Fourier-transform THz-EPR as a method to assign spin-
coupling parameters of high-spin (S> 1/2) systems with very large zero-field splittings. The …
coupling parameters of high-spin (S> 1/2) systems with very large zero-field splittings. The …
Simulating frequency-domain electron paramagnetic resonance: bridging the gap between experiment and magnetic parameters for high-spin transition-metal ion …
We present a comparison of experimental and simulated frequency-and field-domain
electron paramagnetic resonance (EPR) spectra of integer and half-integer high-spin …
electron paramagnetic resonance (EPR) spectra of integer and half-integer high-spin …