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Atom transfer radical polymerization: a mechanistic perspective
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …
Reversed controlled polymerization (RCP): depolymerization from well-defined polymers to monomers
Controlled polymerization methods are well-established synthetic protocols for the design
and preparation of polymeric materials with a high degree of precision over molar mass and …
and preparation of polymeric materials with a high degree of precision over molar mass and …
[HTML][HTML] Bulk depolymerization of poly (methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …
lower temperatures than previously reported methods through the incorporation of …
Bulk depolymerization of methacrylate polymers via pendent group activation
In this study, we present an efficient approach for the depolymerization of poly (methyl
methacrylate)(PMMA) copolymers synthesized via conventional radical polymerization. By …
methacrylate)(PMMA) copolymers synthesized via conventional radical polymerization. By …
Photocatalytic upcycling and depolymerization of vinyl polymers
Photocatalytic upcycling and depolymerization of vinyl polymers have emerged as
promising strategies to combat plastic pollution and promote a circular economy. This mini …
promising strategies to combat plastic pollution and promote a circular economy. This mini …
Toward green atom transfer radical polymerization: current status and future challenges
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Reversing RAFT polymerization: near-quantitative monomer generation via a catalyst-free depolymerization approach
The ability to reverse controlled radical polymerization and regenerate the monomer would
be highly beneficial for both fundamental research and applications, yet this has remained …
be highly beneficial for both fundamental research and applications, yet this has remained …
Photocatalytic ATRP depolymerization: temporal control at low ppm of catalyst concentration
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
Photoassisted radical depolymerization
Controlled radical polymerization techniques enable the synthesis of polymers with
predetermined molecular weights, narrow molecular weight distributions, and controlled …
predetermined molecular weights, narrow molecular weight distributions, and controlled …