The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Over the past three decades, the field of coordination polymers (CPs) and metal–organic
frameworks (MOFs) has developed rapidly due to the potential applications of these …

Reported here is the discovery of a redox‐neutral NiII/NiII catalytic cycle which is capable of
the linear‐selective hydroarylation of unactivated alkenes with arylboronic acids for the first …

The combination of ethylene (E), 1, 3-butadiene (BD), and carbon dioxide (CO2), three
extensively utilized feedstocks, into a polymer via the copolymerization pathway is of great …

The direct dehydrogenation of alkanes is among the most efficient ways to access valuable
alkene products. Although several catalysts have been designed to promote this …

Intermediate amide complexes of NHC-ligated monovalent nickel in Buchwald–Hartwig
amination of aryl halides were isolated and structurally characterized. The amide complexes …

The incorporation of CO2 into organometallic and organic molecules represents a
sustainable way to prepare carboxylates. The mechanism of reductive carboxylation of alkyl …

Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly
substituted and functionalized alkenyl iodides has been developed. The reaction involves …

A Ni-catalyzed enantioconvergent cross-coupling between β-bromostyrenes and secondary
Grignard reagents is reported. This C (sp2)–C (sp3) cross-coupling is applicable to a broad …

Well-defined nickel hydride complexes bearing aryl-substituted α-diimine (i PrDI= N, N′-bis
(2, 6-diisopropylphenyl)-2, 3-butanediimine or MesDI= N, N′-bis (2, 4, 6-trimethylphenyl)-2 …