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Carbon-based metal-free electrocatalysts: from oxygen reduction to multifunctional electrocatalysis
Since the discovery of N-doped carbon nanotubes as the first carbon-based metal-free
electrocatalyst (C-MFEC) for oxygen reduction reaction (ORR) in 2009, C-MFECs have …
electrocatalyst (C-MFEC) for oxygen reduction reaction (ORR) in 2009, C-MFECs have …
Molecular reactions at aqueous interfaces
MF Ruiz-Lopez, JS Francisco… - Nature Reviews …, 2020 - nature.com
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …
Water–solid contact electrification causes hydrogen peroxide production from hydroxyl radical recombination in sprayed microdroplets
Contact electrification between water and a solid surface is crucial for physicochemical
processes at water–solid interfaces. However, the nature of the involved processes remains …
processes at water–solid interfaces. However, the nature of the involved processes remains …
Sprayed water microdroplets are able to generate hydrogen peroxide spontaneously
Ultrapure N2 gas was bubbled through water, and the humidified output containing
undetectable concentrations of ozone filled a closed chamber in which 18 MΩ-cm water was …
undetectable concentrations of ozone filled a closed chamber in which 18 MΩ-cm water was …
Aqueous microdroplets enable abiotic synthesis and chain extension of unique peptide isomers from free amino acids
Amide bond formation, the essential condensation reaction underlying peptide synthesis, is
hindered in aqueous systems by the thermodynamic constraints associated with …
hindered in aqueous systems by the thermodynamic constraints associated with …
Can electric fields drive chemistry for an aqueous microdroplet?
Reaction rates of common organic reactions have been reported to increase by one to six
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …
[HTML][HTML] Interface of biomolecular condensates modulates redox reactions
Biomolecular condensates mediate diverse cellular processes. The density-transition
process of condensate formation results in the selective partitioning of molecules, which …
process of condensate formation results in the selective partitioning of molecules, which …
High electric field on water microdroplets catalyzes spontaneous and ultrafast oxidative C–H/N–H cross-coupling
D Zhang, X Yuan, C Gong, X Zhang - Journal of the American …, 2022 - ACS Publications
Oxidative C–H/N–H cross-coupling has emerged as an atom-economical method for the
construction of C–N bonds. Conventional oxidative C–H/N–H coupling requires at least one …
construction of C–N bonds. Conventional oxidative C–H/N–H coupling requires at least one …
Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events
The formation mechanism of aerosol sulfate during wintertime haze events in China is still
largely unknown. As companions, SO2 and transition metals are mainly emitted from coal …
largely unknown. As companions, SO2 and transition metals are mainly emitted from coal …
Hydrocarbon degradation by contact with anoxic water microdroplets
X Chen, Y **a, Z Zhang, L Hua, X Jia… - Journal of the …, 2023 - ACS Publications
Oils are hydrophobic, but their degradation is frequently found to be accelerated in the
presence of water microdroplets. The direct chemical consequences of water–oil contact …
presence of water microdroplets. The direct chemical consequences of water–oil contact …