Carbon-based metal-free electrocatalysts: from oxygen reduction to multifunctional electrocatalysis

C Hu, R Paul, Q Dai, L Dai - Chemical Society Reviews, 2021 - pubs.rsc.org
Since the discovery of N-doped carbon nanotubes as the first carbon-based metal-free
electrocatalyst (C-MFEC) for oxygen reduction reaction (ORR) in 2009, C-MFECs have …

Molecular reactions at aqueous interfaces

MF Ruiz-Lopez, JS Francisco… - Nature Reviews …, 2020 - nature.com
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …

Water–solid contact electrification causes hydrogen peroxide production from hydroxyl radical recombination in sprayed microdroplets

B Chen, Y **a, R He, H Sang, W Zhang, J Li… - Proceedings of the …, 2022 - pnas.org
Contact electrification between water and a solid surface is crucial for physicochemical
processes at water–solid interfaces. However, the nature of the involved processes remains …

Sprayed water microdroplets are able to generate hydrogen peroxide spontaneously

MA Mehrgardi, M Mofidfar, RN Zare - Journal of the American …, 2022 - ACS Publications
Ultrapure N2 gas was bubbled through water, and the humidified output containing
undetectable concentrations of ozone filled a closed chamber in which 18 MΩ-cm water was …

Aqueous microdroplets enable abiotic synthesis and chain extension of unique peptide isomers from free amino acids

DT Holden, NM Morato, RG Cooks - … of the National Academy of Sciences, 2022 - pnas.org
Amide bond formation, the essential condensation reaction underlying peptide synthesis, is
hindered in aqueous systems by the thermodynamic constraints associated with …

Can electric fields drive chemistry for an aqueous microdroplet?

H Hao, I Leven, T Head-Gordon - Nature communications, 2022 - nature.com
Reaction rates of common organic reactions have been reported to increase by one to six
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …

[HTML][HTML] Interface of biomolecular condensates modulates redox reactions

Y Dai, CF Chamberlayne, MS Messina, CJ Chang… - Chem, 2023 - cell.com
Biomolecular condensates mediate diverse cellular processes. The density-transition
process of condensate formation results in the selective partitioning of molecules, which …

High electric field on water microdroplets catalyzes spontaneous and ultrafast oxidative C–H/N–H cross-coupling

D Zhang, X Yuan, C Gong, X Zhang - Journal of the American …, 2022 - ACS Publications
Oxidative C–H/N–H cross-coupling has emerged as an atom-economical method for the
construction of C–N bonds. Conventional oxidative C–H/N–H coupling requires at least one …

Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events

W Wang, M Liu, T Wang, Y Song, L Zhou, J Cao… - Nature …, 2021 - nature.com
The formation mechanism of aerosol sulfate during wintertime haze events in China is still
largely unknown. As companions, SO2 and transition metals are mainly emitted from coal …

Hydrocarbon degradation by contact with anoxic water microdroplets

X Chen, Y **a, Z Zhang, L Hua, X Jia… - Journal of the …, 2023 - ACS Publications
Oils are hydrophobic, but their degradation is frequently found to be accelerated in the
presence of water microdroplets. The direct chemical consequences of water–oil contact …