Understanding catalyst surfaces during catalysis through near ambient pressure X-ray photoelectron spectroscopy

L Nguyen, FF Tao, Y Tang, J Dou, XJ Bao - Chemical reviews, 2019 - ACS Publications
Heterogeneous catalysis occurs on the surface of a catalyst particle in a gas or liquid
environment of reactants. The surface of the catalyst particle acts as an active chemical …

Surface restructuring and predictive design of heterogeneous catalysts

F Tao, M Salmeron - Science, 2024 - science.org
Heterogeneous catalysts, which often consist of metal nanoparticles loaded on supports
such as metal oxides, can undergo several types of restructuring under reaction and …

Subsurface oxide plays a critical role in CO2 activation by Cu(111) surfaces to form chemisorbed CO2, the first step in reduction of CO2

M Favaro, H **ao, T Cheng… - Proceedings of the …, 2017 - National Acad Sciences
A national priority is to convert CO2 into high-value chemical products such as liquid fuels.
Because current electrocatalysts are not adequate, we aim to discover new catalysts by …

MOF-derived Cu@ Cu2O heterogeneous electrocatalyst with moderate intermediates adsorption for highly selective reduction of CO2 to methanol

X Yang, J Cheng, X Yang, Y Xu, W Sun… - Chemical Engineering …, 2022 - Elsevier
To improve Faradaic efficiency (FE) of CO 2 reduction reaction (CO 2 RR) to methanol over
Cu-based complex electrocatalysts, a novel MOF-derived Cu@ Cu 2 O heterogeneous …

Tuning Cu/Cu2O Interfaces for the Reduction of Carbon Dioxide to Methanol in Aqueous Solutions

X Chang, T Wang, ZJ Zhao, P Yang… - Angewandte Chemie …, 2018 - Wiley Online Library
Artificial photosynthesis can be used to store solar energy and reduce CO2 into fuels to
potentially alleviate global warming and the energy crisis. Compared to the generation of …

Activation of Cu (111) surface by decomposition into nanoclusters driven by CO adsorption

B Eren, D Zherebetskyy, LL Patera, CH Wu, H Bluhm… - Science, 2016 - science.org
The (111) surface of copper (Cu), its most compact and lowest energy surface, became
unstable when exposed to carbon monoxide (CO) gas. Scanning tunneling microscopy …

CO oxidation over CuOx/TiO2 catalyst: The importance of oxygen vacancies and Cu+ species

W Chen, J Xu, F Huang, C Zhao, Y Guan, Y Fang… - Applied Surface …, 2023 - Elsevier
It is well documented that the existence of oxygen vacancies and active Cu species can
improve CO oxidation activity over TiO 2 substrate. Herein, TiO 2-supported copper catalysts …

Metal/oxide interfacial effects on the selective oxidation of primary alcohols

G Zhao, F Yang, Z Chen, Q Liu, Y Ji, Y Zhang… - Nature …, 2017 - nature.com
A main obstacle in the rational development of heterogeneous catalysts is the difficulty in
identifying active sites. Here we show metal/oxide interfacial sites are highly active for the …

A Highly Stable Copper‐Based Catalyst for Clarifying the Catalytic Roles of Cu0 and Cu+ Species in Methanol Dehydrogenation

H Yang, Y Chen, X Cui, G Wang, Y Cen… - Angewandte …, 2018 - Wiley Online Library
Identification of the active copper species, and further illustration of the catalytic mechanism
of Cu‐based catalysts is still a challenge because of the mobility and evolution of Cu0 and …

Tiny Species with Big Impact: High Activity of Cu Single Atoms on CeO2–TiO2 Deciphered by Operando Spectroscopy

J Mosrati, AM Abdel-Mageed, TH Vuong… - ACS …, 2021 - ACS Publications
Cu single-atom catalysts (SACs) supported on CeO2–TiO2 were prepared by a sol–gel
method and tested for CO oxidation between 120 and 350° C. Operando and in situ …