This review deals with two of the most commonly used methods for the preparation of
amines: the reductive amination of aldehydes and ketones and the hydrogenation of nitriles …

N‐Alkylamines are key intermediates in the synthesis of fine chemicals, dyes, and natural
products, and hence are highly valuable building blocks in organic chemistry. Consequently …

Single-electron reduction of a carbonyl to a ketyl enables access to a polarity-reversed
platform of reactivity for this cornerstone functional group. However, the synthetic utility of the …

An in situ-generated complex from [RuCp* Cl2] 2 and dpePhos ligand is reported as an
efficient catalyst in the presence of 5 mol% of LiOtBu for the N-methylation of amines using …

Reductive amination is an important tool for synthetic organic chemists in the construction of
carbon‐nitrogen bonds. This reaction, also termed reductive alkylation, involves …

Reviewing and correlating in detail the synthetic, mechanistic, and physical properties
ofenamines, this reference features an extensive discussion of all enamine literature …

Organolanthanide complexes of the type Cp '2LnCH (SiMe3) 2 (Cp '= η5-Me5C5; Ln= La,
Nd, Sm, Lu) and Me2SiCp ''2LnCH (SiMe3) 2 (Cp ''= η5-Me4C5; Ln= Nd, Sm, Lu) serve as …

Direct and indirect reductive amination of aldehydes and ketones with solid acid-activated
sodium borohydride under solvent-free conditions - ScienceDirect Skip to main contentSkip …

DMSO methylates a broad range of amines in the presence of formic acid, providing a novel,
green and practical method for amine methylation. The protocol also allows the one‐pot …

Dirhodium caprolactamate [Rh2 (cap) 4] is a highly effective catalyst for the oxidative
Mannich reaction. The reaction proceeds via C− H oxidation of a tertiary amine followed by …