Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

High-nuclearity cobalt coordination clusters: Synthetic, topological and magnetic aspects

GE Kostakis, SP Perlepes, VA Blatov… - Coordination Chemistry …, 2012 - Elsevier
Polynuclear coordination clusters of 3d metals continue to attract the intense interest of
scientists from the synthetic inorganic chemistry, bioinorganic chemistry and molecular …

A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene

Y Bi, XT Wang, W Liao, X Wang, X Wang… - Journal of the …, 2009 - ACS Publications
Calixarene-capped Co32 clusters are constructed by a sodalite CoII24 cage and an
encapsulated CoIII8 cube. The spherical units are arranged into three isomeric structures …

Cyanide single-molecule magnets exhibiting solvent dependent reversible “on” and “off” exchange bias behavior

D Pinkowicz, HI Southerland, C Avendaño… - Journal of the …, 2015 - ACS Publications
The syntheses, structures, and magnetic properties of four new complex salts,(PPN){[MnIII
(salphen)(MeOH)] 2 [MIII (CN) 6]}· 7MeOH (Mn2M· 7MeOH)(M= Fe, Ru, Os and Co; PPN+ …

The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies

B Nowicka, T Korzeniak, O Stefańczyk… - Coordination Chemistry …, 2012 - Elsevier
Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

Coordination clusters of 3d-metals that behave as single-molecule magnets (SMMs): synthetic routes and strategies

D Maniaki, E Pilichos, SP Perlepes - Frontiers in Chemistry, 2018 - frontiersin.org
The area of 3d-metal coordination clusters that behave as Single-Molecule Magnets (SMMs)
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …

Family of mixed 3d–4f dimeric 14-metallacrown-5 compounds: syntheses, structures, and magnetic properties

F Cao, S Wang, D Li, S Zeng, M Niu, Y Song… - Inorganic …, 2013 - ACS Publications
An isomorphous family of mixed 3d–4f dodenuclear aggregates,{[MnIII8Ln4 (Clshi) 8 (OAc)
6 (μ3-OCH3) 2 (μ3-O) 2 (CH3OH) 12 (H2O) 2]· 4CH3OH· x H2O)}(where Ln= EuIII (1), GdIII …

First palladium (II) and platinum (II) complexes from employment of 2, 6-diacetylpyridine dioxime: synthesis, structural and spectroscopic characterization, and …

ES Koumousi, M Zampakou, CP Raptopoulou… - Inorganic …, 2012 - ACS Publications
Employment of the monoanion of 2, 6-diacetylpyridine dioxime (dapdoH2) as a tridentate
chelate in palladium (II) and platinum (II) chemistry is reported. The syntheses, crystal …

A polyoxometalate-based single-molecule magnet with a mixed-valent {Mn IV 2 Mn III 6 Mn II 4} core

ZM Zhang, S Yao, YG Li, HH Wu, YH Wang… - Chemical …, 2013 - pubs.rsc.org
A polyoxometalate-based single-molecule magnet with a mixed-valent {Mn IV 2 Mn III 6 Mn II
4 } core - Chemical Communications (RSC Publishing) DOI:10.1039/C3CC38981B Royal …

Smart ligands for efficient 3d-, 4d-and 5d-metal single-molecule magnets and single-ion magnets

PS Perlepe, D Maniaki, E Pilichos, E Katsoulakou… - Inorganics, 2020 - mdpi.com
There has been a renaissance in the interdisciplinary field of Molecular Magnetism since~
2000, due to the discovery of the impressive properties and potential applications of d-and f …