Molecular actinide compounds with soft chalcogen ligands
M Ephritikhine - Coordination Chemistry Reviews, 2016 - Elsevier
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Recent advances in organoactinide chemistry as exemplified by cyclopentadienyl compounds
M Ephritikhine - Organometallics, 2013 - ACS Publications
The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …
representative examples for the description of recent highlights in organometallic and more …
Trends in covalency for d-and f-element metallocene dichlorides identified using chlorine K-edge X-ray absorption spectroscopy and time-dependent density …
We describe the use of Cl K-edge X-ray absorption spectroscopy (XAS) and both ground-
state and time-dependent hybrid density functional theory (DFT) to probe the electronic …
state and time-dependent hybrid density functional theory (DFT) to probe the electronic …
Covalency in CeIV and UIV Halide and N‐Heterocyclic Carbene Bonds
Oxidative halogenation with trityl chloride provides convenient access to CeIV and UIV
chloroamides [M (N {SiMe3} 2) 3Cl] and their N‐heterocyclic carbene derivatives,[M (L)(N …
chloroamides [M (N {SiMe3} 2) 3Cl] and their N‐heterocyclic carbene derivatives,[M (L)(N …
Molecular and electronic structure of dinuclear uranium bis-μ-oxo complexes with diamond core structural motifs
AC Schmidt, FW Heinemann… - Journal of the …, 2014 - ACS Publications
In a multiple-bond metathesis reaction, the triazacyclononane (tacn)-anchored methyl-and
neopentyl (nP)-substituted tris (aryloxide) UIII complex [((nP, MeArO) 3tacn) UIII](1) reacts …
neopentyl (nP)-substituted tris (aryloxide) UIII complex [((nP, MeArO) 3tacn) UIII](1) reacts …
Paramagnetic Properties of [AnIV(NO3)6]2− Complexes (An = U, Np, Pu) Probed by NMR Spectroscopy and Quantum Chemical Calculations
M Autillo, MC Illy, L Briscese, MA Islam… - Inorganic …, 2024 - ACS Publications
Actinide+ IV complexes with six nitrates [AnIV (NO3) 6] 2−(An= Th, U, Np, and Pu) have
been studied by 15N and 17O NMR spectroscopy in solution and first-principles …
been studied by 15N and 17O NMR spectroscopy in solution and first-principles …
Structural and Bonding Analysis in Monomeric Actinide (IV) Oxalate from Th (IV) to Pu (IV): Comparison with the An (IV) Nitrate Series
C Tamain, M Autillo, D Guillaumont, L Guérin… - Inorganic …, 2022 - ACS Publications
Single-crystal X-ray diffraction (SC-XRD) structures and Raman spectra of a series of new
isomorphous molecular An (IV)-oxalate compounds (Th, U, Np, and Pu) are reported. These …
isomorphous molecular An (IV)-oxalate compounds (Th, U, Np, and Pu) are reported. These …
Selectivity of azine ligands toward lanthanide (III)/actinide (III) differentiation: A relativistic DFT based rationalization
Polyazines emerge as highly selective ligands toward actinide versus lanthanide
separation. Electronic structures of several mono-and polyazine f-complexes of general …
separation. Electronic structures of several mono-and polyazine f-complexes of general …
Probing the 5f orbital contribution to the bonding in a U (V) ketimide complex
LA Seaman, G Wu, N Edelstein… - Journal of the …, 2012 - ACS Publications
Reaction of UCl4 with 5 equiv of Li (N CtBuPh) generates the homoleptic U (IV) ketimide
complex [Li (THF) 2][U (N CtBuPh) 5](1) in 71% yield. Similarly, reaction of UCl4 with 5 …
complex [Li (THF) 2][U (N CtBuPh) 5](1) in 71% yield. Similarly, reaction of UCl4 with 5 …
Unusual Actinyl Complexes with a Redox-Active N, S-Donor Ligand
Understanding the fundamental chemistry of soft N, S-donor ligands with actinides across
the series is critical for separation science toward sustainable nuclear energy. This task is …
the series is critical for separation science toward sustainable nuclear energy. This task is …